Chapter 7: Problem 24
The Bohr model only works for one electron species. Why do we discuss it in this text (what's good about it)?
Chapter 7: Problem 24
The Bohr model only works for one electron species. Why do we discuss it in this text (what's good about it)?
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Get started for freeOne of the emission spectral lines for \(\mathrm{Be}^{3+}\) has a wavelength of \(253.4 \mathrm{~nm}\) for an electronic transition that begins in the state with \(n=5 .\) What is the principal quantum number of the lowerenergy state corresponding to this emission? (Hint: The Bohr model can be applied to one- electron ions. Don't forget the \(Z\) factor: \(Z=\) nuclear charge \(=\) atomic number. \()\)
The elements \(\mathrm{Cu}, \mathrm{O}, \mathrm{La}, \mathrm{Y}, \mathrm{Ba}, \mathrm{Tl}\), and \(\mathrm{Bi}\) are all found in high- temperature ceramic superconductors. Write the expected electron configuration for these atoms.
One bit of evidence that the quantum mechanical model is "correct" lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said to exhibit paramagnetism. The degree to which this effect is observed is directly related to the number of unpaired electrons present in the atom. Consider the ground-state electron configurations for \(\mathrm{Li}, \mathrm{N}, \mathrm{Ni}, \mathrm{Te}, \mathrm{Ba}\), and \(\mathrm{Hg} .\) Which of these atoms would be expected to be paramagnetic, and how many unpaired electrons are present in each paramagnetic atom?
A certain oxygen atom has the electron configuration \(1 s^{2} 2 s^{2} 2 p_{x}^{2} 2 p_{y}^{2}\). How many unpaired electrons are present? Is this an excited state of oxygen? In going from this state to the ground state would energy be released or absorbed?
Answer the following questions assuming that \(m_{s}\) could have three values rather than two and that the rules for \(n, \ell\), and \(m_{\ell}\) are the normal ones. a. How many electrons would an orbital be able to hold? b. How many elements would the first and second periods in the periodic table contain? c. How many elements would be contained in the first transition metal series? d. How many electrons would the set of 4 forbitals be able to hold?
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