The Bohr model only works for one electron species. Why do we discuss it in this text (what's good about it)?

Short Answer

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The Bohr model is discussed in physics and chemistry texts due to its simplicity, ease of calculation for hydrogen-like atoms, foundational role in quantum mechanics, its ability to explain spectral lines in the hydrogen atom, and its educational value as an excellent starting point for understanding atomic structure. Even though the model has limitations and has been surpassed by more advanced models like the Schrödinger model, it helps students build a strong foundation for further learning in atomic and quantum physics.

Step by step solution

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1. Introduction to the Bohr Model

The Bohr model, proposed by Niels Bohr in 1913, is an early model of atomic structure and only works for one-electron species like hydrogen and hydrogen-like ions (such as He+ and Li²⁺). The model successfully explains the hydrogen atom's energy levels, electron orbits, and quantized energy emissions.
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2. Simplicity and Calculation

One of the key advantages of the Bohr model is its simplicity. It offers a straightforward way to calculate the energy levels of hydrogen-like atoms. Using the Bohr model, we can easily determine the electron's energy in each orbit around the nucleus using the formula \(E_n = -\frac{13.6 eV}{n^2}\), where n is the principal quantum number (integer n≥1).
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3. Foundation for Quantum Mechanics

Even though the Bohr model has limitations, it sets the stage for the development of quantum mechanics. The idea of quantized energy levels and the wave-particle duality introduced by the model are fundamental concepts in quantum theory. These concepts were further elaborated and refined by scientists like Erwin Schrödinger, Werner Heisenberg, and Max Born, who contributed to the development of the modern quantum mechanics theory.
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4. Spectral Lines of Hydrogen Atom

The Bohr model accurately predicts the hydrogen atoms' spectral lines, also known as the hydrogen emission spectrum. The model explains the observed spectral lines by the electrons absorbing or emitting photons. As the electrons transition between energy levels (orbits), they absorb or emit energy corresponding to the difference in energy levels. This energy difference is observed as discrete lines in the emission spectrum.
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5. Educational Value

Despite its limitations, the Bohr model is widely discussed in educational settings because it serves as an excellent starting point for introducing the concept of atomic structure. The model's simplicity and visualization of electron orbits help students easily grasp the essentials of atomic theory. In conclusion, even though the Bohr model has its limitations, it is discussed in physics and chemistry texts because of its simplicity, ease of calculation, foundational role in quantum mechanics, the explanation of spectral lines in the hydrogen atom, and its educational value. While more advanced models like the Schrödinger model have surpassed the Bohr model, understanding the Bohr model helps students build a strong foundation for further learning in atomic and quantum physics.

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Most popular questions from this chapter

One of the emission spectral lines for \(\mathrm{Be}^{3+}\) has a wavelength of \(253.4 \mathrm{~nm}\) for an electronic transition that begins in the state with \(n=5 .\) What is the principal quantum number of the lowerenergy state corresponding to this emission? (Hint: The Bohr model can be applied to one- electron ions. Don't forget the \(Z\) factor: \(Z=\) nuclear charge \(=\) atomic number. \()\)

The elements \(\mathrm{Cu}, \mathrm{O}, \mathrm{La}, \mathrm{Y}, \mathrm{Ba}, \mathrm{Tl}\), and \(\mathrm{Bi}\) are all found in high- temperature ceramic superconductors. Write the expected electron configuration for these atoms.

One bit of evidence that the quantum mechanical model is "correct" lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said to exhibit paramagnetism. The degree to which this effect is observed is directly related to the number of unpaired electrons present in the atom. Consider the ground-state electron configurations for \(\mathrm{Li}, \mathrm{N}, \mathrm{Ni}, \mathrm{Te}, \mathrm{Ba}\), and \(\mathrm{Hg} .\) Which of these atoms would be expected to be paramagnetic, and how many unpaired electrons are present in each paramagnetic atom?

A certain oxygen atom has the electron configuration \(1 s^{2} 2 s^{2} 2 p_{x}^{2} 2 p_{y}^{2}\). How many unpaired electrons are present? Is this an excited state of oxygen? In going from this state to the ground state would energy be released or absorbed?

Answer the following questions assuming that \(m_{s}\) could have three values rather than two and that the rules for \(n, \ell\), and \(m_{\ell}\) are the normal ones. a. How many electrons would an orbital be able to hold? b. How many elements would the first and second periods in the periodic table contain? c. How many elements would be contained in the first transition metal series? d. How many electrons would the set of 4 forbitals be able to hold?

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