Chapter 8: Problem 39
Write electron configurations for the most stable ion formed by each of the elements Rb, Ba, Se, and I (when in stable ionic compounds).
Chapter 8: Problem 39
Write electron configurations for the most stable ion formed by each of the elements Rb, Ba, Se, and I (when in stable ionic compounds).
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Get started for free\(\operatorname{LiI}(s)\) has a heat of formation of \(-272 \mathrm{~kJ} / \mathrm{mol}\) and a lattice energy of \(-753 \mathrm{~kJ} / \mathrm{mol}\). The ionization energy of \(\mathrm{Li}(g)\) is 520 . \(\mathrm{kJ} / \mathrm{mol}\), the bond energy of \(\mathrm{I}_{2}(g)\) is \(151 \mathrm{~kJ} / \mathrm{mol}\), and the electron affinity of \(\mathrm{I}(g)\) is \(-295 \mathrm{~kJ} / \mathrm{mol}\). Use these data to determine the heat of sublimation of \(\operatorname{Li}(s)\).
For each of the following groups, place the atoms and/or ions in order of decreasing size. a. \(\mathrm{V}, \mathrm{V}^{2+}, \mathrm{V}^{3+}, \mathrm{V}^{5+}\) b. \(\mathrm{Na}^{+}, \mathrm{K}^{+}, \mathrm{Rb}^{+}, \mathrm{Cs}^{+}\) c. \(\mathrm{Te}^{2-}, \mathrm{I}^{-}, \mathrm{Cs}^{+}, \mathrm{Ba}^{2+}\) d. \(\mathrm{P}, \mathrm{P}^{-}, \mathrm{P}^{2-}, \mathrm{P}^{3-}\) e. \(\mathrm{O}^{2-}, \mathrm{S}^{2-}, \mathrm{Se}^{2-}, \mathrm{Te}^{2-}\)
The second electron affinity values for both oxygen and sulfur are unfavorable (endothermic). Explain.
Give an example of an ionic compound where both the anion and the cation are isoelectronic with each of the following noble gases. a. Ne c. \(\mathrm{Kr}\) b. \(\mathrm{Ar}\) d. Xe
Hydrogen has an electronegativity value between boron and carbon and identical to phosphorus. With this in mind, rank the following bonds in order of decreasing polarity: \(\mathrm{P}-\mathrm{H}, \mathrm{O}-\mathrm{H}\), \(\mathrm{N}-\mathrm{H}, \mathrm{F}-\mathrm{H}, \mathrm{C}-\mathrm{H}\)
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