Chapter 8: Problem 49
Give three ions that are isoelectronic with neon. Place these ions in order of increasing size.
Chapter 8: Problem 49
Give three ions that are isoelectronic with neon. Place these ions in order of increasing size.
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Get started for freeWhich of the following statements is(are) true? Correct the false statements. a. The molecules \(\mathrm{SeS}_{3}, \mathrm{SeS}_{2}, \mathrm{PCl}_{5}, \mathrm{TeCl}_{4}, \mathrm{ICl}_{3}\), and \(\mathrm{XeCl}_{2}\) all exhibit at least one bond angle which is approximately \(120^{\circ}\) b. The bond angle in \(\mathrm{SO}_{2}\) should be similar to the bond angle in \(\mathrm{CS}_{2}\) or \(\mathrm{SCl}_{2}\) c. Of the compounds \(\mathrm{CF}_{4}, \mathrm{KrF}_{4}\), and \(\mathrm{SeF}_{4}\), only \(\mathrm{SeF}_{4}\) exhibits an overall dipole moment (is polar). d. Central atoms in a molecule adopt a geometry of the bonded atoms and lone pairs about the central atom in order to maximize electron repulsions.
Oxidation of the cyanide ion produces the stable cyanate ion, \(\mathrm{OCN}^{-}\). The fulminate ion, \(\mathrm{CNO}^{-}\), on the other hand, is very unstable. Fulminate salts explode when struck; \(\mathrm{Hg}(\mathrm{CNO})_{2}\) is used in blasting caps. Write the Lewis structures and assign formal charges for the cyanate and fulminate ions. Why is the fulminate ion so unstable? (C is the central atom in \(\mathrm{OCN}^{-}\) and \(\mathrm{N}\) is the central atom in \(\mathrm{CNO}^{-} .\).)
Consider the following reaction: $$ \mathrm{A}_{2}+\mathrm{B}_{2} \longrightarrow 2 \mathrm{AB} \quad \Delta H=-285 \mathrm{~kJ} $$ The bond energy for \(\mathrm{A}_{2}\) is one-half the amount of the \(\mathrm{AB}\) bond energy. The bond energy of \(\mathrm{B}_{2}=432 \mathrm{~kJ} / \mathrm{mol}\). What is the bond energy of \(\mathrm{A}_{2}\) ?
Use the formal charge arguments to rationalize why \(\mathrm{BF}_{3}\) would not follow the octet rule.
Some of the important pollutants in the atmosphere are ozone \(\left(\mathrm{O}_{3}\right)\), sulfur dioxide, and sulfur trioxide. Write Lewis structures for these three molecules. Show all resonance structures where applicable.
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