Write Lewis structures that obey the octet rule for each of the following molecules. a. \(\mathrm{CCl}_{4}\) c. \(\mathrm{SeCl}_{2}\) b. \(\mathrm{NCl}_{3}\) d. \(\mathrm{ICl}\) In each case, the atom listed first is the central atom.

Short Answer

Expert verified
a. In \(\mathrm{CCl}_{4}\), Carbon (C) forms 4 single bonds with 4 Chlorine (Cl) atoms, each Cl has 3 lone pairs, and the Lewis structure appears as: ``` Cl | Cl -- C -- Cl | Cl ``` c. In \(\mathrm{SeCl}_{2}\), Selenium (Se) forms 2 single bonds with 2 Chlorine (Cl) atoms and has a lone pair, each Cl has 3 lone pairs, and the Lewis structure is: ``` Cl | Se -- Cl ¦ ``` b. In \(\mathrm{NCl}_{3}\), Nitrogen (N) forms 3 single bonds with 3 Chlorine (Cl) atoms and has a lone pair, each Cl has 3 lone pairs, and the Lewis structure appears as: ``` Cl | Cl -- N -- Cl ¦ ``` d. In \(\mathrm{ICl}\), Iodine (I) forms a single bond with the Chlorine (Cl) atom, and both I and Cl have 3 lone pairs each, and the Lewis structure appears as: ``` I -- Cl ¦ ¦ ```

Step by step solution

01

Determine the total number of valence electrons for each molecule

To do this, we need to add the valence electrons of each atom in the molecule. Remember that in the periodic table, group 1 has 1 valence electron, group 2 has 2 valence electrons, and so on. a. \(\mathrm{CCl}_{4}\): Carbon (C) has 4 valence electrons and Chlorine (Cl) has 7 valence electrons each. So, the total valence electrons are \(4 + 4(7) = 32\). c. \(\mathrm{SeCl}_{2}\): Selenium (Se) has 6 valence electrons and Chlorine (Cl) has 7 valence electrons each. So, the total valence electrons are \(6 + 2(7) = 20\). b. \(\mathrm{NCl}_{3}\): Nitrogen (N) has 5 valence electrons and Chlorine (Cl) has 7 valence electrons each. So, the total valence electrons are \(5 + 3(7) = 26\). d. \(\mathrm{ICl}\): Iodine (I) has 7 valence electrons and Chlorine (Cl) has 7 valence electrons. So, the total valence electrons are \(7 + 7 = 14\).
02

Distribute the valence electrons to satisfy the octet rule

We need to distribute the electrons in such a way that each atom is surrounded by eight electrons, either in lone pairs or bond pairs. a. \(\mathrm{CCl}_{4}\): Carbon (C) shares 1 electron with each of the 4 Chlorine (Cl) atoms, forming 4 single bonds. All 4 Chlorine atoms have 3 lone pairs, and Carbon has no lone pairs. c. \(\mathrm{SeCl}_{2}\): Selenium (Se) shares 1 electron with each of the 2 Chlorine (Cl) atoms, forming 2 single bonds. Both Chlorine atoms have 3 lone pairs. However, to complete the octet for Selenium, which has 6 valence electrons, it also needs to have one lone pair. b. \(\mathrm{NCl}_{3}\): Nitrogen (N) shares 1 electron with each of the 3 Chlorine (Cl) atoms, forming 3 single bonds. All 3 Chlorine atoms have 3 lone pairs, and Nitrogen has 1 lone pair. d. \(\mathrm{ICl}\): Iodine (I) shares 1 electron with the Chlorine (Cl) atom, forming a single bond. Both Iodine and Chlorine have 3 lone pairs each.
03

Draw the Lewis structures for each molecule

Now, we will draw the Lewis structures for each molecule, keeping in mind the number of bond pairs and lone pairs discussed in the previous step. a. \(\mathrm{CCl}_{4}\): ``` Cl | Cl -- C -- Cl | Cl ``` c. \(\mathrm{SeCl}_{2}\): ``` Cl | Se -- Cl ¦ ``` b. \(\mathrm{NCl}_{3}\): ``` Cl | Cl -- N -- Cl ¦ ``` d. \(\mathrm{ICl}\): ``` I -- Cl ¦ ¦ ```

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