A solution is prepared by mixing \(75.0 \mathrm{~mL}\) of \(0.020 \mathrm{M} \mathrm{BaCl}_{2}\) and \(125 \mathrm{~mL}\) of \(0.040 \mathrm{M} \mathrm{K}_{2} \mathrm{SO}_{4}\). What are the concentrations of barium and sulfate ions in this solution? Assume only \(\mathrm{SO}_{4}^{2-}\) ions (no \(\left.\mathrm{HSO}_{4}^{-}\right)\) are present.

Short Answer

Expert verified
The final concentrations of barium and sulfate ions in the solution are \(0.0075\,M\) and \(0.025\,M\), respectively.

Step by step solution

01

Find the moles of each ion in the initial solutions

First, we need to calculate the moles of Ba²⁺ and SO₄²⁻ in the initial solutions. For the BaCl₂ solution: \[moles\,of\,Ba^{2+} = volume \times concentration = 75.0\,mL \times 0.020\,M = 1.5\,mmol\] For the K₂SO₄ solution: \[moles\,of\,SO_{4}^{2-} = volume \times concentration = 125\,mL \times 0.040\,M = 5\,mmol\]
02

Calculate the total volume of the final solution

Next, we'll determine the total volume of the final solution, which is the sum of the volumes of the two initial solutions: \[total\,volume\,of\,final\,solution = 75.0\,mL + 125\,mL = 200\,mL\]
03

Divide the moles of each ion by the total volume to find their concentrations

Finally, we will divide the moles of each ion by the total volume to find their concentrations in the final solution: For Ba²⁺ ion: \[concentration\,of\,Ba^{2+} = \frac{moles\,of\,Ba^{2+}}{total\,volume} = \frac{1.5\,mmol}{200\,mL} = 0.0075\,M\] For SO₄²⁻ ion: \[concentration\,of\,SO_{4}^{2-} = \frac{moles\,of\,SO_{4}^{2-}}{total\,volume} = \frac{5\,mmol}{200\,mL} = 0.025\,M\] Therefore, the final concentrations of barium and sulfate ions in the solution are 0.0075 M and 0.025 M, respectively.

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