Chapter 18: Problem 2
In making a specific galvanic cell, explain how one decides on the electrodes and the solutions to use in the cell.
Chapter 18: Problem 2
In making a specific galvanic cell, explain how one decides on the electrodes and the solutions to use in the cell.
All the tools & learning materials you need for study success - in one app.
Get started for freeDirect methanol fuel cells (DMFCs) have shown some promise as a viable option for providing "green" energy to small electrical devices. Calculate \(\mathscr{E}^{\circ}\) for the reaction that takes place in DMFCs: $$ \mathrm{CH}_{3} \mathrm{OH}(l)+3 / 2 \mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ Use values of \(\Delta G_{\mathrm{f}}^{\circ}\) from Appendix \(4 .\)
Aluminum is produced commercially by the electrolysis of \(\mathrm{Al}_{2} \mathrm{O}_{3}\) in the presence of a molten salt. If a plant has a continuous capacity of \(1.00\) million A, what mass of aluminum can be produced in \(2.00 \mathrm{~h}\) ?
The solubility product for \(\operatorname{CuI}(s)\) is \(1.1 \times 10^{-12}\). Calculate the value of \(\mathscr{E}^{\circ}\) for the half-reaction $$ \operatorname{CuI}(s)+\mathrm{e}^{-} \longrightarrow \mathrm{Cu}(s)+\mathrm{I}^{-}(a q) $$
The overall reaction in the lead storage battery is \(\mathrm{Pb}(s)+\mathrm{PbO}_{2}(s)+2 \mathrm{H}^{+}(a q)+2 \mathrm{HSO}_{4}^{-}(a q) \longrightarrow\) \(2 \mathrm{PbSO}_{4}(s)+2 \mathrm{H}_{2} \mathrm{O}(l)\) a. For the cell reaction \(\Delta H^{\circ}=-315.9 \mathrm{~kJ}\) and \(\Delta S^{\circ}=\) \(263.5 \mathrm{~J} / \mathrm{K}\). Calculate \(\mathscr{E}^{\circ}\) at \(-20 .{ }^{\circ} \mathrm{C}\). Assume \(\Delta H^{\circ}\) and \(\Delta S^{\circ}\) do not depend on temperature. b. Calculate \(\mathscr{E}\) at \(-20 .{ }^{\circ} \mathrm{C}\) when \(\left[\mathrm{HSO}_{4}{ }^{-}\right]=\left[\mathrm{H}^{+}\right]=4.5 M\). c. Consider your answer to Exercise 71 . Why does it seem that batteries fail more often on cold days than on warm days?
In the electrolysis of an aqueous solution of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\), what reactions occur at the anode and the cathode (assuming standard conditions)?
What do you think about this solution?
We value your feedback to improve our textbook solutions.