Chapter 19: Problem 47
The mass defect for a lithium-6 nucleus is \(-0.03434 \mathrm{~g} / \mathrm{mol}\). Calculate the atomic mass of \({ }^{6} \mathrm{Li}\)
Chapter 19: Problem 47
The mass defect for a lithium-6 nucleus is \(-0.03434 \mathrm{~g} / \mathrm{mol}\). Calculate the atomic mass of \({ }^{6} \mathrm{Li}\)
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Get started for freeA positron and an electron can annihilate each other on colliding, producing energy as photons: $$ { }_{-1}^{0} \mathrm{e}+{ }_{+1}^{0} \mathrm{e} \longrightarrow 2{ }^{0}{ }_{0}^{0} \gamma $$ Assuming that both \(\gamma\) rays have the same energy, calculate the wavelength of the electromagnetic radiation produced.
The only stable isotope of fluorine is fluorine-19. Predict possible modes of decay for fluorine-21, fluorine-18, and fluorine- \(17 .\)
Zirconium is one of the few metals that retains its structural integrity upon exposure to radiation. The fuel rods in most nuclear reactors therefore are often made of zirconium. Answer the following questions about the redox properties of zirconium based on the half-reaction \(\mathrm{ZrO}_{2} \cdot \mathrm{H}_{2} \mathrm{O}+\mathrm{H}_{2} \mathrm{O}+4 \mathrm{e}^{-} \longrightarrow \mathrm{Zr}+4 \mathrm{OH}^{-} \quad \mathscr{E}^{\circ}=-2.36 \mathrm{~V}\) a. Is zirconium metal capable of reducing water to form hydrogen gas at standard conditions? b. Write a balanced equation for the reduction of water by zirconium. c. Calculate \(\mathscr{E}^{\circ}, \Delta G^{\circ}\), and \(K\) for the reduction of water by zirconium metal. d. The reduction of water by zirconium occurred during the accidents at Three Mile Island in \(1979 .\) The hydrogen produced was successfully vented and no chemical explosion occurred. If \(1.00 \times 10^{3} \mathrm{~kg}\) Zr reacts, what mass of \(\mathrm{H}_{2}\) is produced? What volume of \(\mathrm{H}_{2}\) at \(1.0 \mathrm{~atm}\) and \(1000 .{ }^{\circ} \mathrm{C}\) is produced? e. At Chernobyl in 1986, hydrogen was produced by the reaction of superheated steam with the graphite reactor core: $$ \mathrm{C}(s)+\mathrm{H}_{2} \mathrm{O}(g) \longrightarrow \mathrm{CO}(g)+\mathrm{H}_{2}(g) $$
Natural uranium is mostly nonfissionable \({ }^{238} \mathrm{U} ;\) it contains only about \(0.7 \%\) of fissionable \({ }^{235} \mathrm{U}\). For uranium to be useful as a nuclear fuel, the relative amount of \({ }^{235} \mathrm{U}\) must be increased to about \(3 \%\). This is accomplished through a gas diffusion process. In the diffusion process, natural uranium reacts with fluorine to form a mixture of \({ }^{238} \mathrm{UF}_{6}(g)\) and \({ }^{235} \mathrm{UF}_{6}(g)\). The fluoride mixture is then enriched through a multistage diffusion process to produce a \(3 \%^{235} \mathrm{U}\) nuclear fuel. The diffusion process utilizes Graham's law of effusion (see Chapter 5, Section 5.7). Explain how Graham's law of effusion allows natural uranium to be enriched by the gaseous diffusion process.
Strontium-90 and radon-222 both pose serious health risks. \({ }^{90} \mathrm{Sr}\) decays by \(\beta\) -particle production and has a relatively long half-life (28.9 years). Radon-222 decays by \(\alpha\) -particle production and has a relatively short half-life (3.82 days). Explain why each decay process poses health risks.
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