Chapter 20: Problem 25
Consider element \(113 .\) What is the expected electron configuration for element 113 ? What oxidation states would be exhibited by element 113 in its compounds?
Chapter 20: Problem 25
Consider element \(113 .\) What is the expected electron configuration for element 113 ? What oxidation states would be exhibited by element 113 in its compounds?
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Get started for freeSlaked lime, \(\mathrm{Ca}(\mathrm{OH})_{2}\), is used to soften hard water by removing calcium ions from hard water through the reaction \(\mathrm{Ca}(\mathrm{OH})_{2}(a q)+\mathrm{Ca}^{2+}(a q)+2 \mathrm{HCO}_{3}^{-}(a q) \rightarrow\) \(2 \mathrm{CaCO}_{3}(s)+2 \mathrm{H}_{2} \mathrm{O}(l)\) Although \(\mathrm{CaCO}_{3}(s)\) is considered insoluble, some of it does dissolve in aqueous solutions. Calculate the molar solubility of \(\mathrm{CaCO}_{3}\) in water \(\left(K_{\text {sp }}=8.7 \times 10^{-9}\right)\).
Many structures of phosphorus-containing compounds are drawn with some \(\mathrm{P}=\mathrm{O}\) bonds. These bonds are not the typical \(\pi\) bonds we've considered, which involve the overlap of two \(p\) orbitals. Instead, they result from the overlap of a \(d\) orbital on the phosphorus atom with a \(p\) orbital on oxygen. This type of \(\pi\) bonding is sometimes used as an explanation for why \(\mathrm{H}_{3} \mathrm{PO}_{3}\) has the first structure below rather than the second: Draw a picture showing how a \(d\) orbital and a \(p\) orbital overlap to form a \(\pi\) bond.
Phosphoric acid \(\left(\mathrm{H}_{3} \mathrm{PO}_{4}\right)\) is a triprotic acid, phosphorous acid \(\left(\mathrm{H}_{3} \mathrm{PO}_{3}\right)\) is a diprotic acid, and hypophosphorous acid \(\left(\mathrm{H}_{3} \mathrm{PO}_{2}\right)\) is a monoprotic acid. Explain this phenomenon.
What is the molecular structure for each of the following molecules or ions? a. \(\mathrm{OCl}_{2}\) b. \(\mathrm{ClO}_{4}^{-}\) c. \(\mathrm{ICl}_{5}\) d. \(\mathrm{PF}_{6}^{-}\)
Boron hydrides were once evaluated for possible use as rocket fuels. Complete and balance the following equation for the combustion of diborane. $$ \mathrm{B}_{2} \mathrm{H}_{6}(g)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{B}(\mathrm{OH})_{3}(s) $$
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