Chapter 21: Problem 19
What causes high-altitude sickness, and what is high-altitude acclimatization?
Chapter 21: Problem 19
What causes high-altitude sickness, and what is high-altitude acclimatization?
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Get started for freeA metal ion in a high-spin octahedral complex has two more unpaired electrons than the same ion does in a low-spin octahedral complex. Name some possible metal ions for which this would be true.
The complex ion \(\mathrm{Fe}(\mathrm{CN})_{6}{ }^{3-}\) is paramagnetic with one unpaired electron. The complex ion \(\mathrm{Fe}(\mathrm{SCN})_{6}{ }^{3-}\) has five unpaired electrons. Where does \(\mathrm{SCN}^{-}\) lie in the spectrochemical series relative to \(\mathrm{CN}^{-}\) ?
a. In the absorption spectrum of the complex ion \(\mathrm{Cr}(\mathrm{NCS})_{6}{ }^{3-}\), there is a band corresponding to the absorption of a photon of light with an energy of \(1.75 \times 10^{4} \mathrm{~cm}^{-1}\). Given \(1 \mathrm{~cm}^{-1}=\) \(1.986 \times 10^{-23} \mathrm{~J}\), what is the wavelength of this photon? b. The \(\mathrm{Cr}-\mathrm{N}-\mathrm{C}\) bond angle in \(\mathrm{Cr}(\mathrm{NCS})_{6}{ }^{3-}\) is predicted to be \(180^{\circ}\). What is the hybridization of the \(\mathrm{N}\) atom in the \(\mathrm{NCS}^{-}\) ligand when a Lewis acid-base reaction occurs between \(\mathrm{Cr}^{3+}\) and \(\mathrm{NCS}^{-}\) that would give a \(180^{\circ}\) \(\mathrm{Cr}-\mathrm{N}-\mathrm{C}\) bond angle? \(\mathrm{Cr}(\mathrm{NCS})_{6}{ }^{3-}\) undergoes sub- stitution by ethylenediamine (en) according to the equation $$ \mathrm{Cr}(\mathrm{NCS})_{6}^{3-}+2 \mathrm{en} \longrightarrow \mathrm{Cr}(\mathrm{NCS})_{2}(\mathrm{en})_{2}^{+}+4 \mathrm{NCS}^{-} $$ Does \(\mathrm{Cr}(\mathrm{NCS})_{2}(\mathrm{en})_{2}^{+}\) exhibit geometric isomerism? Does \(\mathrm{Cr}(\mathrm{NCS})_{2}(\mathrm{en})_{2}^{+}\) exhibit optical isomerism?
Which is more likely to be paramagnetic, \(\mathrm{Fe}(\mathrm{CN})_{6}{ }^{4-}\) or \(\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+} ?\) Explain.
A blast furnace is used to reduce iron oxides to elemental iron. The reducing agent for this reduction process is carbon monoxide. a. Given the following data: \(\begin{aligned} \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) & \longrightarrow 2 \mathrm{Fe}(s)+3 \mathrm{CO}_{2}(g) & & \Delta H^{\circ}=-23 \mathrm{~kJ} \\ 3 \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(g) & \longrightarrow 2 \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}_{2}(g) & & \Delta H^{\circ}=-39 \mathrm{~kJ} \\ \mathrm{Fe}_{3} \mathrm{O}_{4}(s)+\mathrm{CO}(g) & \longrightarrow 3 \mathrm{FeO}(s)+\mathrm{CO}_{2}(g) & & \Delta H^{\circ}=18 \mathrm{~kJ} \end{aligned}\) determine \(\Delta H^{\circ}\) for the reaction $$ \mathrm{FeO}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g) $$ b. The \(\mathrm{CO}_{2}\) produced in a blast furnace during the reduction process actually can oxidize iron into \(\mathrm{FeO}\). To eliminate this reaction, excess coke is added to convert \(\mathrm{CO}_{2}\) into \(\mathrm{CO}\) by the reaction $$ \mathrm{CO}_{2}(g)+\mathrm{C}(s) \longrightarrow 2 \mathrm{CO}(g) $$ Using data from Appendix 4 , determine \(\Delta H^{\circ}\) and \(\Delta S^{\circ}\) for this reaction. Assuming \(\Delta H^{\circ}\) and \(\Delta S^{\circ}\) do not depend on temperature, at what temperature is the conversion reaction of \(\mathrm{CO}_{2}\) into CO spontaneous at standard conditions?
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