Chapter 3: Problem 2
What information do we get from a chemical formula? From a chemical equation?
Chapter 3: Problem 2
What information do we get from a chemical formula? From a chemical equation?
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Get started for freeThe aspirin substitute, acetaminophen \(\left(\mathrm{C}_{8} \mathrm{H}_{9} \mathrm{O}_{2} \mathrm{~N}\right)\), is produced by the following three-step synthesis: I. \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{3} \mathrm{~N}(s)+3 \mathrm{H}_{2}(g)+\mathrm{HCl}(a q) \longrightarrow\) $$ \mathrm{C}_{6} \mathrm{H}_{3} \mathrm{ONCl}(s)+2 \mathrm{H}_{2} \mathrm{O}(t) $$ II. \(\mathrm{C}_{6} \mathrm{H}_{8} \mathrm{ONCl}(s)+\mathrm{NaOH}(a q) \longrightarrow\) $$ \mathrm{C}_{6} \mathrm{H}_{7} \mathrm{ON}(s)+\mathrm{H}_{2} \mathrm{O}(t)+\mathrm{NaCl}(a q) $$ III. \(\mathrm{C}_{6} \mathrm{H}_{7} \mathrm{ON}(s)+\mathrm{C}_{4} \mathrm{H}_{6} \mathrm{O}_{3}(l) \longrightarrow\) $$ \mathrm{C}_{8} \mathrm{H}_{9} \mathrm{O}_{2} \mathrm{~N}(s)+\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}(l) $$ The first two reactions have percent yields of \(87 \%\) and \(98 \%\) by mass, respectively. The overall reaction yields 3 moles of acetaminophen product for every 4 moles of \(\mathrm{C}_{6} \mathrm{H}_{3} \mathrm{O}_{3} \mathrm{~N}\) reacted. a. What is the percent yield by mass for the overall process? b. What is the percent yield by mass of Step III?
Maleic acid is an organic compound composed of \(41.39 \% \mathrm{C}\). \(3.47 \% \mathrm{H}\), and the rest oxygen. If \(0.129\) mole of maleic acid has a mass of \(15.0 \mathrm{~g}\), what are the empirical and molecular formulas of maleic acid?
A compound that contains only carbon, hydrogen, and oxygen is \(48.64 \% \mathrm{C}\) and \(8.16 \% \mathrm{H}\) by mass. What is the empirical formula of this substance?
Give the balanced equation for each of the following chemical reactions: a. Glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) reacts with oxygen gas to produce gaseous carbon dioxide and water vapor. b. Solid iron(III) sulfide reacts with gaseous hydrogen chloride to form solid iron(III) chloride and hydrogen sulfide gas. c. Carbon disulfide liquid reacts with ammonia gas to produce hydrogen sulfide gas and solid ammonium thiocyanate \(\left(\mathrm{NH}_{4} \mathrm{SCN}\right)\).
Glass is a mixture of several compounds, but a major constituent of most glass is calcium silicate, \(\mathrm{CaSiO}_{3-}\) Glass can be etched by treatment with hydrofluoric acid; HF attacks the calcium silicate of the glass, producing gaseous and water-soluble products (which can be removed by washing the glass). For example, the volumetric glassware in chemistry laboratories is often graduated by using this process. Balance the following equation for the reaction of hydrofluoric acid with calcium silicate. $$ \mathrm{CaSiO}_{3}(s)+\mathrm{HF}(a q) \longrightarrow \mathrm{CaF}_{2}(a q)+\mathrm{SiF}_{4}(g)+\mathrm{H}_{2} \mathrm{O}(l) $$
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