The element europium exists in nature as two isotopes: \({ }^{151} \mathrm{Eu}\) has a mass of \(150.9196 \mathrm{u}\) and \({ }^{153} \mathrm{Eu}\) has a mass of \(152.9209 \mathrm{u}\). The average atomic mass of europium is \(151.96 \mathrm{u} .\) Calculate the relative abundance of the two europium isotopes.

Short Answer

Expert verified
The relative abundance of \({ }^{151} \mathrm{Eu}\) is approximately 47.97% and the relative abundance of \({ }^{153} \mathrm{Eu}\) is approximately 52.03%.

Step by step solution

01

Define the variables for the relative abundance of each isotope

Let x be the relative abundance of \({ }^{151} \mathrm{Eu}\) and y be the relative abundance of \({ }^{153} \mathrm{Eu}\). Since these are the only two isotopes, their relative abundances sum up to 100% or 1, so we can write: x + y = 1
02

Set up the equation relating average atomic mass and individual atomic masses

Using the given data and the relationship between the average atomic mass and the individual atomic masses with their relative abundance, the equation is: 151.96 = (150.9196 × x) + (152.9209 × y)
03

Solve the equations for the relative abundance of each isotope

Now we have a system of two linear equations with two variables, x and y: 1. x + y = 1 2. 151.96 = (150.9196 × x) + (152.9209 × y) From equation (1), we can obtain x as follows: x = 1 - y Now, substitute x in equation (2): 151.96 = (150.9196 × (1 - y)) + (152.9209 × y) Expand and rearrange to solve for y: 151.96 = 150.9196 - 150.9196y + 152.9209y 151.96 = 150.9196 + 2.0013y Now, solve for y: 2.0013y = 151.96 - 150.9196 y = \(\frac{1.0404}{2.0013}\) y ≈ 0.5203 Now, substitute the value of y back into the equation for x: x = 1 - 0.5203 x ≈ 0.4797 Thus, the relative abundance of \({ }^{151} \mathrm{Eu}\) (x) is approximately 47.97% and the relative abundance of \({ }^{153} \mathrm{Eu}\) (y) is approximately 52.03%.

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