Maleic acid is an organic compound composed of \(41.39 \% \mathrm{C}\). \(3.47 \% \mathrm{H}\), and the rest oxygen. If \(0.129\) mole of maleic acid has a mass of \(15.0 \mathrm{~g}\), what are the empirical and molecular formulas of maleic acid?

Short Answer

Expert verified
The empirical formula of maleic acid is CHO, and its molecular formula is C4H4O4.

Step by step solution

01

Calculate the moles of each element in maleic acid

We know that maleic acid has \(41.39\% \mathrm{C}\), \(3.47\% \mathrm{H}\), and the rest is oxygen. So, we can write these percentages as grams of each element in 100 g of maleic acid: Carbon: 41.39 g Hydrogen: 3.47 g Oxygen: 100 - 41.39 - 3.47 = 55.14 g Now, divide the grams of each element by its molar mass to get the number of moles: moles of Carbon: \(\frac{41.39}{12.01} = 3.448\) moles of Hydrogen: \(\frac{3.47}{1.008} = 3.444\) moles of Oxygen: \(\frac{55.14}{16.00} = 3.446\)
02

Determine the whole-number ratio (Empirical formula)

Divide each mole value by the smallest mole value to get the ratio of each element in the empirical formula: Carbon: \(\frac{3.448}{3.444} = 1\) Hydrogen: \(\frac{3.444}{3.444} = 1\) Oxygen: \(\frac{3.446}{3.444} = 1\) The whole-number ratio is 1:1:1. Thus, the empirical formula is CHO.
03

Calculate Molecular Formula

First, we will find the molar mass of the empirical formula: Empirical formula molar mass: \(12.01\mathrm{C} + 1.008\mathrm{H} + 16.00\mathrm{O} = 29.018\, \mathrm{g/mol}\) Given that 0.129 moles of maleic acid have a mass of 15.0 g, we can calculate the molar mass of maleic acid: Molar mass of maleic acid = \(\frac{15.0\, \mathrm{g}}{0.129\, \mathrm{mol}} = 116.28\, \mathrm{g/mol}\) Now, divide the molar mass of maleic acid by the molar mass of its empirical formula to find the whole-number multiple: Multiple: \(\frac{116.28}{29.018} \approx 4\) Finally, multiply the empirical formula by the whole-number multiple to get the molecular formula: C(1 x 4)H(1 x 4)O(1 x 4) = C4H4O4 Therefore, the molecular formula of maleic acid is C4H4O4.

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Most popular questions from this chapter

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