Calculate the molarity of each of these solutions. a. A 5.623-g sample of \(\mathrm{NaHCO}_{3}\) is dissolved in enough water to make \(250.0 \mathrm{~mL}\) of solution. b. A \(184.6-\mathrm{mg}\) sample of \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) is dissolved in enough water to make \(500.0 \mathrm{~mL}\) of solution. c. A \(0.1025-\mathrm{g}\) sample of copper metal is dissolved in \(35 \mathrm{~mL}\) of concentrated \(\mathrm{HNO}_{3}\) to form \(\mathrm{Cu}^{2+}\) ions and then water is added to make a total volume of \(200.0 \mathrm{~mL}\). (Calculate the molarity of \(\mathrm{Cu}^{2+}\).)

Short Answer

Expert verified
The molarities of the solutions are as follows: a. \(0.26776\text{ M}\) for the NaHCO3 solution b. \(0.001255\text{ M}\) for the K2Cr2O7 solution c. \(0.00807\text{ M}\) for the Cu²⁺ ions in solution

Step by step solution

01

Find the moles of NaHCO3

First, we need to find the molar mass of NaHCO3. Molar mass of NaHCO3 = 22.99(g/mol for Na) + 1.01(g/mol for H) + 12.01(g/mol for C) + 3 * 16.00(g/mol for O) = 84.01 g/mol Now, we'll find the moles of NaHCO3 by dividing the mass by the molar mass: moles of NaHCO3 = 5.623 g / 84.01 g/mol = 0.06694 mol
02

Convert volume to liters

We need to convert the volume of the solution from mL to L: 250 mL = 250/1000 = 0.250 L
03

Calculate molarity

Now we can find the molarity using the formula: Molarity (M) = moles of solute / volume of solution in L Molarity (M) = 0.06694 mol / 0.250 L = 0.26776 M #b. Finding the molarity of K2Cr2O7 solution#
04

Find the moles of K2Cr2O7

First, find the molar mass of K2Cr2O7. Molar mass of K2Cr2O7 = 2 * 39.10(g/mol for K) + 2 * 51.996(g/mol for Cr) + 7 * 16.00(g/mol for O) = 294.18 g/mol Next, convert the mass from mg to g: 184.6 mg = 184.6 / 1000 = 0.1846 g Now, find the moles of K2Cr2O7 by dividing the mass by the molar mass: moles of K2Cr2O7 = 0.1846 g / 294.18 g/mol = 0.0006274 mol
05

Convert volume to liters

We need to convert the volume of the solution from mL to L: 500 mL = 500/1000 = 0.500 L
06

Calculate molarity

Now we can find the molarity using the formula: Molarity (M) = moles of solute / volume of solution in L Molarity (M) = 0.0006274 mol / 0.500 L = 0.001255 M #c. Finding the molarity of Cu²⁺ ions in solution#
07

Find the moles of Cu

First, find the molar mass of Cu. Molar mass of Cu = 63.546 g/mol Now, find the moles of Cu by dividing the mass by the molar mass: moles of Cu = 0.1025 g / 63.546 g/mol = 0.001614 mol
08

Convert volume to liters

We need to convert the total volume of the solution from mL to L: 200 mL = 200/1000 = 0.200 L
09

Calculate molarity

Now we can find the molarity using the formula: Molarity (M) = moles of solute / volume of solution in L Molarity (M) = 0.001614 mol / 0.200 L = 0.00807 M

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