Which of the following solutions of strong electrolytes contains the largest number of moles of chloride ions: \(100.0 \mathrm{~mL}\) of \(0.30 \mathrm{M} \mathrm{AlCl}_{3}, 50.0 \mathrm{~mL}\) of \(0.60 \mathrm{M} \mathrm{MgCl}_{2}\), or \(200.0 \mathrm{~mL}\) of \(0.40 \mathrm{M} \mathrm{NaCl} ?\)

Short Answer

Expert verified
The solution with the largest number of moles of chloride ions is \(100.0 \mathrm{~mL}\) of $0.30 \mathrm{M} \mathrm{AlCl}_{3}$, which contains 0.09 moles of Cl⁻.

Step by step solution

01

Identify the dissociation of the strong electrolytes

Each of the strong electrolytes given will dissociate completely in the solution, producing respective ions. We can write the dissociation reaction as: AlCl₃ ↔ Al³⁺ + 3Cl⁻ MgCl₂ ↔ Mg²⁺ + 2Cl⁻ NaCl ↔ Na⁺ + Cl⁻
02

Calculate the moles of chloride ions produced by each electrolyte

To find the moles of chloride ions produced by each electrolyte, we'll follow this formula: moles of Cl⁻ = [concentration (M) * volume (L)] * (moles of Cl⁻ / moles of electrolyte) Make sure to convert the given volume from mL to L by dividing the volume by 1000.
03

Calculate the moles of chloride ions in the AlCl₃ solution

Using the given concentration and volume of AlCl₃ solution: moles of Cl⁻ = [0.30 M * (100.0 mL / 1000)] * 3 moles of Cl⁻ = 0.09 moles
04

Calculate the moles of chloride ions in the MgCl₂ solution

Using the given concentration and volume of MgCl₂ solution: moles of Cl⁻ = [0.60 M * (50.0 mL / 1000)] * 2 moles of Cl⁻ = 0.06 moles
05

Calculate the moles of chloride ions in the NaCl solution

Using the given concentration and volume of NaCl solution: moles of Cl⁻ = [0.40 M * (200.0 mL / 1000)] * 1 moles of Cl⁻ = 0.08 moles
06

Compare the moles of chloride ions for each solution

Now that we've calculated the moles of chloride ions for each electrolyte solution, we can compare them to see which one has the highest value. AlCl₃: 0.09 moles Cl⁻ MgCl₂: 0.06 moles Cl⁻ NaCl: 0.08 moles Cl⁻ Out of these values, the AlCl₃ solution contains the largest number of moles of chloride ions (0.09 moles). Therefore, \(100.0 \mathrm{~mL}\) of $0.30 \mathrm{M} \mathrm{AlCl}_{3}$ contains the largest number of moles of chloride ions.

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