Chapter 5: Problem 15
How does Dalton's law of partial pressures help us with our model of ideal gases? That is, what postulates of the kinetic molecular theory does it support?
Chapter 5: Problem 15
How does Dalton's law of partial pressures help us with our model of ideal gases? That is, what postulates of the kinetic molecular theory does it support?
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Get started for freeConsider the following reaction: $$ 4 \mathrm{Al}(s)+3 \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{Al}_{2} \mathrm{O}_{3}(s) $$ It takes \(2.00 \mathrm{~L}\) of pure oxygen gas at STP to react completely with a certain sample of aluminum. What is the mass of aluminum reacted?
We state that the ideal gas law tends to hold best at low pressures and high temperatures. Show how the van der Waals equation simplifies to the ideal gas law under these conditions.
Urea \(\left(\mathrm{H}_{2} \mathrm{NCONH}_{2}\right)\) is used extensively as a nitrogen source in fertilizers. It is produced commercially from the reaction of ammonia and carbon dioxide: $$ 2 \mathrm{NH}_{3}(g)+\mathrm{CO}_{2}(g) \underset{\text { Pressure }}{\text { Heat }}{\mathrm{H}}_{2} \mathrm{NCONH}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(g) $$ Ammonia gas at \(223^{\circ} \mathrm{C}\) and \(90 .\) atm flows into a reactor at a rate of \(500 . \mathrm{L} / \mathrm{min}\). Carbon dioxide at \(223^{\circ} \mathrm{C}\) and 45 atm flows into the reactor at a rate of \(600 . \mathrm{L} / \mathrm{min} .\) What mass of urea is produced per minute by this reaction assuming \(100 \%\) yield?
Sulfur trioxide, \(\mathrm{SO}_{3}\), is produced in enormous quantities each year for use in the synthesis of sulfuric acid. $$ \begin{aligned} \mathrm{S}(s)+\mathrm{O}_{2}(g) & \longrightarrow \mathrm{SO}_{2}(g) \\ 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow & 2 \mathrm{SO}_{3}(g) \end{aligned} $$ What volume of \(\mathrm{O}_{2}(g)\) at \(350 .{ }^{\circ} \mathrm{C}\) and a pressure of \(5.25 \mathrm{~atm}\) is needed to completely convert \(5.00 \mathrm{~g}\) sulfur to sulfur trioxide?
A \(15.0\) -L rigid container was charged with \(0.500\) atm of krypton gas and \(1.50\) atm of chlorine gas at \(350 .{ }^{\circ} \mathrm{C}\). The krypton and chlorine react to form krypton tetrachloride. What mass of krypton tetrachloride can be produced assuming \(100 \%\) yield?
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