A balloon is filled to a volume of \(7.00 \times 10^{2} \mathrm{~mL}\) at a temperature of \(20.0^{\circ} \mathrm{C}\). The balloon is then cooled at constant pressure to a temperature of \(1.00 \times 10^{2} \mathrm{~K}\). What is the final volume of the balloon?

Short Answer

Expert verified
Using Charles's law formula, \(\frac{V_1}{T_1} = \frac{V_2}{T_2}\), with the given initial volume of \(7.00 \times 10^{2} \mathrm{~mL}\) and initial and final temperatures, we find the final volume of the balloon to be approximately \(238.84 \mathrm{~mL}\).

Step by step solution

01

Convert temperatures to Kelvin

First, we need to convert the initial temperature from Celsius to Kelvin. We can do this by adding 273.15 to the given temperature in Celsius. \[T_1 = 20.0 + 273.15 = 293.15 ~\mathrm{K}\]
02

Setup Charles's Law formula

Now that we have both temperatures in Kelvin, we can plug the given values into the Charles's law formula: \[ \frac{V_1}{T_1} = \frac{V_2}{T_2} \] \[ \frac{7.00 \times 10^{2} \mathrm{~mL}}{293.15 \mathrm{~K}} = \frac{V_2}{1.00 \times 10^{2} \mathrm{~K}} \]
03

Solve for final volume

Now we'll solve for the final volume (\(V_2\)): \[ V_2 = \frac{7.00 \times 10^{2} \mathrm{~mL}}{293.15 \mathrm{~K}} \times 1.00 \times 10^{2} \mathrm{~K} \]
04

Calculate final volume

Perform the multiplication: \[ V_2 = 700 \mathrm{~mL} \times \frac{1}{2.9315} \] \[ V_2 \approx 238.84 \mathrm{~mL} \] So, the final volume of the balloon after cooling it to \(1.00 \times 10^{2} \mathrm{~K}\) is approximately \(238.84 \mathrm{~mL}\).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Laws
Understanding how gases behave under different conditions is essential for a wide range of scientific applications. The gas laws are a set of rules that predict how a gas will change when pressure, volume, and temperature are varied. One of the fundamental gas laws is Charles's Law, which states that the volume of a gas is directly proportional to its temperature when pressure is held constant.

This means that if you increase the temperature of a gas, its volume will increase as well, provided the amount of gas and the pressure remain constant. Similarly, if the temperature decreases, the volume of the gas will also decrease. Charles's Law is mathematically expressed as \( \frac{V_1}{T_1} = \frac{V_2}{T_2} \), where \(V_1\) and \(V_2\) are the initial and final volumes, and \(T_1\) and \(T_2\) are the initial and final temperatures in Kelvin, respectively.

Understanding Charles's Law is not only crucial in scientific research but also has practical applications, such as explaining how hot air balloons rise and why car tires can burst in the heat if overinflated.
Temperature Conversion
Working with gas laws often requires converting temperatures from one scale to another. In many scientific calculations, including those involving Charles's Law, temperature must be measured in Kelvin, which is the SI unit for thermodynamic temperature. There's a simple relationship between the Celsius and Kelvin scales:

\( K = ^{\circ}C + 273.15 \)

What's crucial to remember is that Kelvin is an absolute scale, meaning it starts at absolute zero, which is the theoretical temperature at which all kinetic motion of particles stops. This conversion is essential because using degrees Celsius could result in negative volume values in calculations, which are not physically meaningful for gases. For Fahrenheit to Kelvin, you would first convert Fahrenheit to Celsius and then to Kelvin using the following steps:

\( ^{\circ}C = (^{\circ}F - 32) \times \frac{5}{9} \)
\( K = ^{\circ}C + 273.15 \)

Accurate temperature conversion is key to correctly applying the gas laws and obtaining meaningful results in your experiments or calculations.
Volume-Temperature Relationship
Charles's Law illustrates the volume-temperature relationship for gases, clarifying that this relationship is linear when plotted on a graph with volume on the y-axis and temperature on the x-axis. When visualizing this, imagine that as a balloon heats up, the gas particles inside move faster and take up more space, causing the balloon to expand and hence, increase its volume.

This linear correlation implies that the temperatures must be expressed in absolute terms, which, as mentioned earlier, uses the Kelvin scale where zero reflects the complete absence of thermal energy. To fully understand the implications of this relationship, one can perform thought experiments or real-life experiments, such as heating a fixed amount of gas in a sealed container and observing the volume increase.

The practical aspect of this knowledge is significant. For instance, engineers must consider these laws when designing engines and storage containers for gases. At the same time, weather forecasters may use them to predict changes in weather patterns caused by the expansion and contraction of gases in the atmosphere.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Consider two different containers, each filled with 2 moles of \(\mathrm{Ne}(\mathrm{g})\). One of the containers is rigid and has constant volume. The other container is flexible (like a balloon) and is capable of changing its volume to keep the external pressure and internal pressure equal to each other. If you raise the temperature in both containers, what happens to the pressure and density of the gas inside each container? Assume a constant external pressure.

Silane, \(\mathrm{SiH}_{4}\), is the silicon analogue of methane, \(\mathrm{CH}_{4}\). It is prepared industrially according to the following equations: $$ \begin{aligned} \mathrm{Si}(s)+3 \mathrm{HCl}(g) & \longrightarrow \operatorname{HSiCl}_{3}(l)+\mathrm{H}_{2}(g) \\ 4 \mathrm{HSiCl}_{3}(l) & \longrightarrow \mathrm{SiH}_{4}(g)+3 \mathrm{SiCl}_{4}(l) \end{aligned} $$ a. If \(156 \mathrm{~mL} \mathrm{HSiCl}_{3}(d=1.34 \mathrm{~g} / \mathrm{mL})\) is isolated when \(15.0 \mathrm{~L}\) \(\mathrm{HCl}\) at \(10.0 \mathrm{~atm}\) and \(35^{\circ} \mathrm{C}\) is used, what is the percent yield of \(\mathrm{HSiCl}_{3}\) ? b. When \(156 \mathrm{~mL} \mathrm{HSiCl}_{3}\) is heated, what volume of \(\mathrm{SiH}_{4}\) at \(10.0\) atm and \(35^{\circ} \mathrm{C}\) will be obtained if the percent yield of the reaction is \(93.1 \%\) ?

The rate of effusion of a particular gas was measured and found to be \(24.0 \mathrm{~mL} / \mathrm{min}\). Under the same conditions, the rate of effusion of pure methane \(\left(\mathrm{CH}_{4}\right)\) gas is \(47.8 \mathrm{~mL} / \mathrm{min}\). What is the molar mass of the unknown gas?

A container is filled with an ideal gas to a pressure of \(11.0\) atm at \(0^{\circ} \mathrm{C}\). a. What will be the pressure in the container if it is heated to \(45^{\circ} \mathrm{C} ?\) b. At what temperature would the pressure be \(6.50 \mathrm{~atm}\) ? c. At what temperature would the pressure be \(25.0 \mathrm{~atm}\) ?

Some very effective rocket fuels are composed of lightweight liquids. The fuel composed of dimethylhydrazine \(\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{~N}_{2} \mathrm{H}_{2}\right]\) mixed with dinitrogen tetroxide was used to power the Lunar Lander in its missions to the moon. The two components react according to the following equation: \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{~N}_{2} \mathrm{H}_{2}(l)+2 \mathrm{~N}_{2} \mathrm{O}_{4}(l) \longrightarrow 3 \mathrm{~N}_{2}(g)+4 \mathrm{H}_{2} \mathrm{O}(g)+2 \mathrm{CO}_{2}(g)\) If \(150 \mathrm{~g}\) dimethylhydrazine reacts with excess dinitrogen tetroxide and the product gases are collected at \(127^{\circ} \mathrm{C}\) in an evacuated 250-L tank, what is the partial pressure of nitrogen gas produced and what is the total pressure in the tank assuming the reaction has \(100 \%\) yield?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free