The partial pressure of \(\mathrm{CH}_{4}(g)\) is \(0.175 \mathrm{~atm}\) and that of \(\mathrm{O}_{2}(g)\) is \(0.250\) atm in a mixture of the two gases. a. What is the mole fraction of each gas in the mixture? b. If the mixture occupies a volume of \(10.5 \mathrm{~L}\) at \(65^{\circ} \mathrm{C}\), calculate the total number of moles of gas in the mixture. c. Calculate the number of grams of each gas in the mixture.

Short Answer

Expert verified
a. Calculate the mole fraction of each gas: Step 1: Total pressure, \(P_{total} = 0.175 + 0.250 = 0.425\) atm Step 2: Mole fractions: \(X_{CH4} = \frac{0.175}{0.425} = 0.412\) and \(X_{O2} = \frac{0.250}{0.425} = 0.588\) b. Calculate the total number of moles of gas in the mixture: Step 3: \(T (K) = 65 ^\circ C + 273.15 = 338.15 K\) Step 4: \(n = \frac{PV}{RT} = \frac{(0.425 \mathrm{~atm})(10.5 \mathrm{~L})}{(0.0821 \frac{\mathrm{L\cdot atm}}{\mathrm{mol\cdot K}})(338.15 \mathrm{~K})} = 0.179\) mol c. Calculate the number of grams of each gas in the mixture: Step 5: Moles of CH4 = \(0.412 * 0.179 = 0.0737\) mol Moles of O2 = \(0.588 * 0.179 = 0.105\) mol Step 6: Mass of CH4 (grams) = \(0.0737\,\mathrm{mol} * 16.04 \frac{\mathrm{g}}{\mathrm{mol}} = 1.18 \mathrm{~g}\) Mass of O2 (grams) = \(0.105\,\mathrm{mol} * 32.00 \frac{\mathrm{g}}{\mathrm{mol}} = 3.36 \mathrm{~g}\)

Step by step solution

01

Calculate the total pressure

Add the partial pressures of each gas to find the total pressure of the gas mixture: \(P_{total} = P_{CH_4} + P_{O_2}\)
02

Calculate the mole fraction of each gas

Divide the pressure of each gas by the total pressure: Mole fraction of CH4 (X_{CH4}) = \(\frac{P_{CH_4}}{P_{total}}\) Mole fraction of O2 (X_{O2}) = \(\frac{P_{O_2}}{P_{total}}\) b. Calculate the total number of moles of gas in the mixture:
03

Convert the temperature to Kelvin

In the Ideal Gas Law, the temperature must be in Kelvin, so convert the given temperature from Celsius to Kelvin: T (K) = 65 °C + 273.15
04

Use Ideal Gas Law to find total moles

Rearrange the Ideal Gas Law to solve for total moles (n): n = \(\frac{PV}{RT}\) Since we have P_total, V, R (gas constant), and T, we can find the total number of moles (n). c. Calculate the number of grams of each gas in the mixture:
05

Calculate moles of each gas using mole fraction

Use the mole fraction and total moles to find the moles of each gas: Moles of CH4 = X_{CH4} * total moles Moles of O2 = X_{O2} * total moles
06

Convert moles to grams using molar mass

Use the molar mass of each gas to convert the moles to grams: Molar mass of CH4 = 16.04 g/mol Molar mass of O2 = 32.00 g/mol Miles of CH4 (grams) = Moles of CH4 * Molar mass of CH4 Miles of O2 (grams) = Moles of O2 * Molar mass of O2

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Most popular questions from this chapter

Consider a \(1.0\) -L container of neon gas at STP. Will the average kinetic energy, average velocity, and frequency of collisions of gas molecules with the walls of the container increase, decrease, or remain the same under each of the following conditions? a. The temperature is increased to \(100^{\circ} \mathrm{C}\). b. The temperature is decreased to \(-50^{\circ} \mathrm{C}\). c. The volume is decreased to \(0.5 \mathrm{~L}\). d. The number of moles of neon is doubled.

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