What is meant by the term lower in energy? Which is lower in energy, a mixture of hydrogen and oxygen gases or liquid water? How do you know? Which of the two is more stable? How do you know?

Short Answer

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The term "lower in energy" refers to a state of a system where its overall potential energy is lower compared to another state, generally making it more stable. In this case, liquid water is lower in energy and more stable than a mixture of hydrogen and oxygen gases. This is because the formation of water from hydrogen and oxygen gases is an exothermic reaction, releasing energy (\(\Delta _rH^{\circ} = -285.8\:kJ/mol\)), and systems in lower energy states are considered more stable due to their decreased reactivity.

Step by step solution

01

Define "Lower in Energy"

The term "lower in energy" refers to a state of a system where its overall potential energy is lower compared to another state. In chemistry, compounds or mixtures with lower energy states are generally more stable, as they release energy in the form of heat or light during the process of achieving that state.
02

Comparing Energy States of the Two Systems

Here, we have two systems: (1) a mixture of hydrogen and oxygen gases, and (2) liquid water. In the first system, hydrogen and oxygen exist as individual gas molecules. In the second system, hydrogen and oxygen have combined to form water molecules. To compare the energy states of these two systems, we can investigate their relative energy release when they form the other system.
03

Formation of Water from Hydrogen and Oxygen Gases

When hydrogen and oxygen gases react to form water, the following chemical reaction takes place: \[2H_2(g) + O_2(g) \rightarrow 2H_2O(l)\] This reaction is exothermic, meaning it releases energy (in the form of heat) during the process. The negative standard enthalpy change (ΔH) for this reaction indicates that the system is losing energy: \[\Delta _rH^{\circ} = -285.8\:kJ/mol\] The fact that energy is released during this reaction means that liquid water has a lower energy state than a mixture of hydrogen and oxygen gases.
04

Stability Comparison

In general, systems in a lower energy state are considered more stable because they tend to be less reactive and require an input of energy to undergo changes. Since liquid water has a lower energy state than a mixture of hydrogen and oxygen gases, it is considered more stable. This stability can be observed in daily life, as liquid water is far less prone to spontaneous combustion or explosion than a mixture of hydrogen and oxygen gases. In summary, liquid water is lower in energy and more stable than a mixture of hydrogen and oxygen gases. This conclusion is based on the energy released during the reaction between hydrogen and oxygen gases to form water molecules and the general concept that lower energy states correlate with increased stability.

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