Chapter 6: Problem 21
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?
Chapter 6: Problem 21
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?
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Get started for freeWhich of the following substances have an enthalpy of formation equal to zero? a. \(\mathrm{Cl}_{2}(g)\) b. \(\mathrm{H}_{2}(g)\) c. \(\mathrm{N}_{2}(l)\) d. \(\mathrm{Cl}(g)\)
Consider a mixture of air and gasoline vapor in a cylinder with a piston. The original volume is \(40 . \mathrm{cm}^{3}\). If the combustion of this mixture releases 950. J of energy, to what volume will the gases expand against a constant pressure of 650 . torr if all the energy of combustion is converted into work to push back the piston?
A piston performs work of \(210 . \mathrm{L} \cdot \mathrm{atm}\) on the surroundings, while the cylinder in which it is placed expands from \(10 . \mathrm{L}\) to \(25 \mathrm{~L}\). At the same time, \(45 \mathrm{~J}\) of heat is transferred from the surroundings to the system. Against what pressure was the piston working?
On Easter Sunday, April 3,1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: \(2 \mathrm{HNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{CO}_{3}(s) \longrightarrow 2 \mathrm{NaNO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)\) a. Calculate \(\Delta H^{\circ}\) for this reaction. Approximately \(2.0 \times\) \(10^{4}\) gal nitric acid was spilled. Assume that the acid was an aqueous solution containing \(70.0 \% \mathrm{HNO}_{3}\) by mass with a density of \(1.42 \mathrm{~g} / \mathrm{cm}^{3} .\) What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? ( \(\Delta H_{\mathrm{f}}^{\circ}\) for \(\left.\mathrm{NaNO}_{3}(a q)=-467 \mathrm{~kJ} / \mathrm{mol}\right)\) b. According to The Denver Post for April 4,1983 , authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of \(\Delta H^{\circ}\), what was their major concern?
Given the following data $$ \begin{aligned} 2 \mathrm{O}_{3}(g) & \longrightarrow 3 \mathrm{O}_{2}(g) & \Delta H &=-427 \mathrm{~kJ} \\ \mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{O}(g) & \Delta H &=495 \mathrm{~kJ} \\ \mathrm{NO}(g)+\mathrm{O}_{3}(g) & \longrightarrow \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g) & \Delta H=-199 \mathrm{~kJ} \end{aligned} $$ calculate \(\Delta H\) for the reaction $$ \mathrm{NO}(g)+\mathrm{O}(g) \longrightarrow \mathrm{NO}_{2}(g) $$
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