Chapter 6: Problem 23
What is incomplete combustion of fossil fuels? Why can this be a problem?
Chapter 6: Problem 23
What is incomplete combustion of fossil fuels? Why can this be a problem?
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Get started for freeWhich of the following processes are exothermic? a. \(\mathrm{N}_{2}(g) \longrightarrow 2 \mathrm{~N}(g)\) b. \(\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(s)\) c. \(\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{Cl}(g)\) d. \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)\) e. \(\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{O}(g)\)
A balloon filled with \(39.1\) moles of helium has a volume of \(876 \mathrm{~L}\) at \(0.0^{\circ} \mathrm{C}\) and \(1.00\) atm pressure. The temperature of the balloon is increased to \(38.0^{\circ} \mathrm{C}\) as it expands to a volume of \(998 \mathrm{~L}\), the pressure remaining constant. Calculate \(q, w\), and \(\Delta E\) for the helium in the balloon. (The molar heat capacity for helium gas is \(20.8 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{mol}\).)
Nitromethane, \(\mathrm{CH}_{3} \mathrm{NO}_{2}\), can be used as a fuel. When the liquid is burned, the (unbalanced) reaction is mainly $$ \mathrm{CH}_{3} \mathrm{NO}_{2}(l)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+\mathrm{N}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ a. The standard enthalpy change of reaction \(\left(\Delta H_{\mathrm{rxn}}^{\circ}\right)\) for the balanced reaction (with lowest whole- number coefficients) is \(-1288.5 \mathrm{~kJ}\). Calculate \(\Delta H_{\mathrm{f}}^{\circ}\) for nitromethane. b. A \(15.0\) - \(\mathrm{L}\) flask containing a sample of nitromethane is filled with \(\mathrm{O}_{2}\) and the flask is heated to \(100 .{ }^{\circ} \mathrm{C}\). At this temperature, and after the reaction is complete, the total pressure of all the gases inside the flask is 950 . torr. If the mole fraction of nitrogen \(\left(\chi_{\text {nitrogen }}\right)\) is \(0.134\) after the reaction is complete, what mass of nitrogen was produced?
In which of the following systems is(are) work done by the surroundings on the system? Assume pressure and temperature are constant. a. \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{SO}_{3}(g)\) b. \(\mathrm{CO}_{2}(s) \longrightarrow \mathrm{CO}_{2}(g)\) c. \(4 \mathrm{NH}_{3}(g)+7 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{NO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)\) d. \(\mathrm{N}_{2} \mathrm{O}_{4}(g) \longrightarrow 2 \mathrm{NO}_{2}(g)\) e. \(\mathrm{CaCO}_{3}(s) \longrightarrow \mathrm{CaCO}(s)+\mathrm{CO}_{2}(g)\)
Calculate \(\Delta H\) for the reaction $$ \mathrm{N}_{2} \mathrm{H}_{4}(l)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{N}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ given the following data: $$ \begin{array}{cr} \text { Equation } & \Delta H(\mathrm{k}\rfloor) \\ 2 \mathrm{NH}_{3}(g)+3 \mathrm{~N}_{2} \mathrm{O}(g) \longrightarrow 4 \mathrm{~N}_{2}(g)+3 \mathrm{H}_{2} \mathrm{O}(I) & -1010 \\ \mathrm{~N}_{2} \mathrm{O}(g)+3 \mathrm{H}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{H}_{4}(I)+\mathrm{H}_{2} \mathrm{O}(I) & -317 \\ 2 \mathrm{NH}_{3}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{H}_{4}(I)+\mathrm{H}_{2} \mathrm{O}(I) & -143 \\ \mathrm{H}_{2}(\mathrm{~g})+\frac{1}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{O}(I) & -286 \end{array} $$
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