Chapter 6: Problem 33
If the internal energy of a thermodynamic system is increased by \(300 . \mathrm{J}\) while \(75 \mathrm{~J}\) of expansion work is done, how much heat was transferred and in which direction, to or from the system?
Chapter 6: Problem 33
If the internal energy of a thermodynamic system is increased by \(300 . \mathrm{J}\) while \(75 \mathrm{~J}\) of expansion work is done, how much heat was transferred and in which direction, to or from the system?
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The Ostwald process for the commercial production of nitric acid from ammonia and oxygen involves the following steps: $$ \begin{aligned} 4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) & \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) \\ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{NO}_{2}(g) \\ 3 \mathrm{NO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l) & \longrightarrow 2 \mathrm{HNO}_{3}(a q)+\mathrm{NO}(g) \end{aligned} $$ a. Use the values of \(\Delta H_{\mathrm{f}}^{\circ}\) in Appendix 4 to calculate the value of \(\Delta H^{\circ}\) for each of the preceding reactions. b. Write the overall equation for the production of nitric acid by the Ostwald process by combining the preceding equations. (Water is also a product.) Is the overall reaction exothermic or endothermic?
A coffee-cup calorimeter initially contains \(125 \mathrm{~g}\) water at \(24.2^{\circ} \mathrm{C}\). Potassium bromide \((10.5 \mathrm{~g})\), also at \(24.2^{\circ} \mathrm{C}\), is added to the water, and after the KBr dissolves, the final temperature is \(21.1^{\circ} \mathrm{C}\). Calculate the enthalpy change for dissolving the salt in \(\mathrm{J} / \mathrm{g}\) and \(\mathrm{kJ} / \mathrm{mol}\). Assume that the specific heat capacity of the solution is \(4.18 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) and that no heat is transferred to the surroundings or to the calorimeter.
Consider the following statements: "Heat is a form of energy, and energy is conserved. The heat lost by a system must be equal to the amount of heat gained by the surroundings. Therefore, heat is conserved." Indicate everything you think is correct in these statements. Indicate everything you think is incorrect. Correct the incorrect statements and explain.
Which of the following processes are exothermic? a. \(\mathrm{N}_{2}(g) \longrightarrow 2 \mathrm{~N}(g)\) b. \(\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(s)\) c. \(\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{Cl}(g)\) d. \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)\) e. \(\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{O}(g)\)
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