Chapter 6: Problem 8
Explain why oceanfront areas generally have smaller temperature fluctuations than inland areas.
Chapter 6: Problem 8
Explain why oceanfront areas generally have smaller temperature fluctuations than inland areas.
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Get started for freeA swimming pool, \(10.0 \mathrm{~m}\) by \(4.0 \mathrm{~m}\), is filled with water to a depth of \(3.0 \mathrm{~m}\) at a temperature of \(20.2^{\circ} \mathrm{C}\). How much energy is required to raise the temperature of the water to \(24.6^{\circ} \mathrm{C} ?\)
Write reactions for which the enthalpy change will be a. \(\Delta H_{\mathrm{f}}^{\circ}\) for solid aluminum oxide. b. the standard enthalpy of combustion of liquid ethanol, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l) .\) c. the standard enthalpy of neutralization of sodium hydroxide solution by hydrochloric acid. d. \(\Delta H_{\mathrm{f}}^{\circ}\) for gaseous vinyl chloride, \(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{Cl}(\mathrm{g})\). e. the enthalpy of combustion of liquid benzene, \(\mathrm{C}_{6} \mathrm{H}_{6}(l)\). f. the enthalpy of solution of solid ammonium bromide.
You have a 1.00-mole sample of water at \(-30 .{ }^{\circ} \mathrm{C}\) and you heat it until you have gaseous water at \(140 .{ }^{\circ} \mathrm{C}\). Calculate \(q\) for the entire process. Use the following data. Specific heat capacity of ice \(=2.03 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) Specific heat capacity of water \(=4.18 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) Specific heat capacity of steam \(=2.02 \mathrm{~J} /{ }^{\circ} \mathrm{C} \cdot \mathrm{g}\) \(\mathrm{H}_{2} \mathrm{O}(s) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l) \quad \Delta H_{\text {fusion }}=6.02 \mathrm{~kJ} / \mathrm{mol}\left(\right.\) at \(\left.0^{\circ} \mathrm{C}\right)\) \(\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(g) \quad \Delta H_{\text {vaporization }}=40.7 \mathrm{~kJ} / \mathrm{mol}\left(\right.\) at \(\left.100 .^{\circ} \mathrm{C}\right)\)
On Easter Sunday, April 3,1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: \(2 \mathrm{HNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{CO}_{3}(s) \longrightarrow 2 \mathrm{NaNO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)\) a. Calculate \(\Delta H^{\circ}\) for this reaction. Approximately \(2.0 \times\) \(10^{4}\) gal nitric acid was spilled. Assume that the acid was an aqueous solution containing \(70.0 \% \mathrm{HNO}_{3}\) by mass with a density of \(1.42 \mathrm{~g} / \mathrm{cm}^{3} .\) What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? ( \(\Delta H_{\mathrm{f}}^{\circ}\) for \(\left.\mathrm{NaNO}_{3}(a q)=-467 \mathrm{~kJ} / \mathrm{mol}\right)\) b. According to The Denver Post for April 4,1983 , authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of \(\Delta H^{\circ}\), what was their major concern?
Consider \(5.5 \mathrm{~L}\) of a gas at a pressure of \(3.0 \mathrm{~atm}\) in a cylinder with a movable piston. The external pressure is changed so that the volume changes to \(10.5 \mathrm{~L}\). a. Calculate the work done, and indicate the correct sign. b. Use the preceding data but consider the process to occur in two steps. At the end of the first step, the volume is \(7.0 \mathrm{~L}\). The second step results in a final volume of \(10.5 \mathrm{~L}\). Calculate the work done, and indicate the correct sign. c. Calculate the work done if after the first step the volume is \(8.0 \mathrm{~L}\) and the second step leads to a volume of \(10.5 \mathrm{~L}\). Does the work differ from that in part b? Explain.
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