For each of the following pairs of elements \((\mathrm{C}\) and \(\mathrm{N})\) \((\mathrm{Ar}\) and \(\mathrm{Br})\) pick the atom with a. more favorable (exothermic) electron affinity. b. higher ionization energy. c. larger size.

Short Answer

Expert verified
For the pair (C and N): a. N has a more favorable electron affinity. b. N has a higher ionization energy. c. C has a larger atomic size. For the pair (Ar and Br): a. Br has a more favorable electron affinity. b. Ar has a higher ionization energy. c. Br has a larger atomic size.

Step by step solution

01

Pair 1: C and N

First, let's analyze the pair of atoms, Carbon (C) and Nitrogen (N). They are both in the same period (period 2). a. Since N is to the right of C in period 2, it has a more favorable (exothermic) electron affinity. b. N is closer to the top right corner, so it has a higher ionization energy. c. C is larger in size compared to N, as the size decreases across a period.
02

Pair 2: Ar and Br

Next, let's analyze the pair of atoms, Argon (Ar) and Bromine (Br). They are both in the same group (group 18, noble gases, and group 17, halogens, respectively). a. Since Ar is a noble gas, it has no electron affinity, while Br has a favorable (exothermic) electron affinity. b. Ar is in a higher period (period 3) compared to Br (period 4), so Ar should have a higher ionization energy. c. Br is lower on the periodic table (period 4) compared to Ar (period 3), so Br has a larger atomic size.
03

Summary of the answers

For the pair (Carbon and Nitrogen): a. Nitrogen has a more favorable electron affinity. b. Nitrogen has a higher ionization energy. c. Carbon has a larger atomic size. For the pair (Argon and Bromine): a. Bromine has a more favorable electron affinity. b. Argon has a higher ionization energy. c. Bromine has a larger atomic size.

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