Give one example of a compound having a linear molecular structure that has an overall dipole moment (is polar) and one example that does not have an overall dipole moment (is nonpolar). Do the same for molecules that have trigonal planar and tetrahedral molecular structures.

Short Answer

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Linear Polar: Hydrogen chloride (HCl) is an example of a linear polar compound due to the difference in electronegativities (H: 2.1, Cl: 3.0) forming an overall dipole. Linear Nonpolar: Carbon dioxide (CO2) is an example of a linear nonpolar compound, as the equal electronegativities of the oxygen atoms cause the dipoles to cancel each other out. Trigonal Planar Polar: Sulfur trioxide (SO3) is an example of a trigonal planar polar compound, with the difference in electronegativities between sulfur and oxygen creating an overall dipole moment. Trigonal Planar Nonpolar: Boron trifluoride (BF3) is an example of a trigonal planar nonpolar compound, as the dipoles cancel each other out due to the symmetry of the trigonal planar structure. Tetrahedral Polar: Ammonia (NH3) is an example of a tetrahedral polar compound, with the electronegativity difference between nitrogen and hydrogen resulting in an overall dipole moment. Tetrahedral Nonpolar: Methane (CH4) is an example of a tetrahedral nonpolar compound, as the molecule contains only nonpolar C-H bonds and the electronegativities of carbon and hydrogen are equal.

Step by step solution

01

Linear Polar Compound

An example of a linear polar compound is hydrogen chloride (HCl). In this molecule, hydrogen (H) has an electronegativity of 2.1 and chlorine (Cl) has an electronegativity of 3.0. Due to the difference in electronegativities, an overall dipole is formed, making the compound polar.
02

Linear Nonpolar Compound

An example of a linear nonpolar compound is carbon dioxide (CO2). In this molecule, the two oxygen (O) atoms have the same electronegativity (3.5), which makes the dipoles cancel each other out, resulting in a nonpolar compound.
03

Trigonal Planar Polar Compound

An example of a trigonal planar polar compound is boron trifluoride (BF3). In this molecule, although the bond between boron (B) and each fluorine (F) atom is polar, due to the symmetry of the trigonal planar structure, the dipoles cancel each other, and the molecule is considered nonpolar.
04

Trigonal Planar Nonpolar Compound

An example of a trigonal planar nonpolar compound is sulfur trioxide (SO3). In this molecule, the electronegativity difference between sulfur (S) and oxygen (O) results in an overall dipole moment, making the compound polar.
05

Tetrahedral Polar Compound

An example of a tetrahedral polar compound is methane (CH4). In this molecule, the four hydrogen (H) atoms have the same electronegativity (2.1) as carbon (C), and since the compound contains only nonpolar C-H bonds, the molecule is considered nonpolar.
06

Tetrahedral Nonpolar Compound

An example of a tetrahedral nonpolar compound is ammonia (NH3). In this molecule, the electronegativity difference between nitrogen (N) and hydrogen (H) creates a polar molecule, as there is an overall dipole moment.

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Most popular questions from this chapter

A common trait of simple organic compounds is to have Lewis structures where all atoms have a formal charge of zero. Consider the following incomplete Lewis structure for an organic compound called methyl cyanoacrylate, the main ingredient in Super Glue. Draw a complete Lewis structure for methyl cyanoacrylate in which all atoms have a formal charge of zero.

For each of the following groups, place the atoms and/or ions in order of decreasing size. a. \(\mathrm{V}, \mathrm{V}^{2+}, \mathrm{V}^{3+}, \mathrm{V}^{5+}\) b. \(\mathrm{Na}^{+}, \mathrm{K}^{+}, \mathrm{Rb}^{+}, \mathrm{Cs}^{+}\) c. \(\mathrm{Te}^{2-}, \mathrm{I}^{-}, \mathrm{Cs}^{+}, \mathrm{Ba}^{2+}\) d. \(\mathrm{P}, \mathrm{P}^{-}, \mathrm{P}^{2-}, \mathrm{P}^{3-}\) e. \(\mathrm{O}^{2-}, \mathrm{S}^{2-}, \mathrm{Se}^{2-}, \mathrm{Te}^{2-}\)

Without using Fig. \(8.3\), predict which bond in each of the following groups will be the most polar. a. \(\mathrm{C}-\mathrm{F}, \mathrm{Si}-\mathrm{F}, \mathrm{Ge}-\mathrm{F}\) b. \(\mathrm{P}-\mathrm{Cl}\) or \(\mathrm{S}-\mathrm{Cl}\) c. \(\mathrm{S}-\mathrm{F}, \mathrm{S}-\mathrm{Cl}, \mathrm{S}-\mathrm{Br}\) d. \(\mathrm{Ti}-\mathrm{Cl}, \mathrm{Si}-\mathrm{Cl}, \mathrm{Ge}-\mathrm{Cl}\)

Which of the following incorrectly shows the bond polarity? Show the correct bond polarity for those that are incorrect. a. \(\delta^{+} \mathrm{H}-\mathrm{F}^{\delta-}\) d. \(^{\delta+} \mathrm{Br}-\mathrm{Br}^{\delta-}\) b. \(^{\delta+} \mathrm{Cl}-\mathrm{I}^{\delta-}\) e. \(^{\delta+} \mathrm{O}-\mathrm{P}^{\delta-}\) c. \(\delta+\mathrm{Si}-\mathrm{S}^{\delta-}\)

Use bond energies to estimate \(\Delta H\) for the combustion of one mole of acetylene: $$ \mathrm{C}_{2} \mathrm{H}_{2}(g)+\frac{5}{2} \mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$

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