Write Lewis structures that obey the octet rule (duet rule for H) for each of the following molecules. a. \(\mathrm{H}_{2} \mathrm{CO}\) b. \(\mathrm{CO}_{2}\) c. \(\mathrm{HCN}\) Carbon is the central atom in all of these molecules.

Short Answer

Expert verified
The Lewis structures for the given molecules that obey the octet rule (duet rule for H) are as follows: a. \(\mathrm{H}_{2}\mathrm{CO}\): H - C = O b. \(\mathrm{CO}_{2}\): O = C = O c. \(\mathrm{HCN}\): H - C ≡ N

Step by step solution

01

Calculate Valence Electrons for Each Atom

Determine the number of valence electrons for each atom in the molecule, using the following periodic groups: Group 1 elements: 1 valence electron Group 2 elements: 2 valence electrons Group 13 elements: 3 valence electrons Group 14 elements: 4 valence electrons Group 15 elements: 5 valence electrons Group 16 elements: 6 valence electrons Group 17 elements: 7 valence electrons
02

Connect Atoms with Single Bonds

Before distributing the remaining electrons, it's important to connect each of the atoms with single bonds.
03

Distribute the Remaining Electrons

Finally, distribute the remaining electrons among the atoms so that they follow the octet rule (or duet rule for Hydrogen). a. \(\mathrm{H}_{2}\mathrm{CO}\): Step 1: Calculate Valence Electrons for Each Atom - \(\mathrm{H}\) has 1 valence electron (x2 since there are 2 hydrogens) - \(\mathrm{C}\) has 4 valence electrons - \(\mathrm{O}\) has 6 valence electrons Total valence electrons: 1(2) + 4 + 6 = 12 Step 2: Connect Atoms with Single Bonds Connect the carbon atom with each of the hydrogen atoms and the oxygen atom using single bonds. Step 3: Distribute the Remaining Electrons After forming the single bonds, we are left with 12 - 2(2) - 2 = 6 electrons. We distribute these electrons onto the oxygen atom to satisfy its octet rule. The Lewis structure for \(\mathrm{H}_{2}\mathrm{CO}\) is: H - C = O b. \(\mathrm{CO}_{2}\): Step 1: Calculate Valence Electrons for Each Atom - \(\mathrm{C}\) has 4 valence electrons - \(\mathrm{O}\) has 6 valence electrons (x2 since there are 2 oxygens) Total valence electrons: 4 + 6(2) = 16 Step 2: Connect Atoms with Single Bonds Connect the carbon atom with each of the oxygen atoms using single bonds. Step 3: Distribute the Remaining Electrons After forming the single bonds, we are left with 16 - 2(2) = 12 electrons. We distribute these electrons by forming double bonds between carbon and each of the oxygen atoms. The Lewis structure for \(\mathrm{CO}_{2}\) is: O = C = O c. \(\mathrm{HCN}\): Step 1: Calculate Valence Electrons for Each Atom - \(\mathrm{H}\) has 1 valence electron - \(\mathrm{C}\) has 4 valence electrons - \(\mathrm{N}\) has 5 valence electrons Total valence electrons: 1 + 4 + 5 = 10 Step 2: Connect Atoms with Single Bonds Connect the hydrogen atom with the carbon atom and the carbon atom with the nitrogen atom using single bonds. Step 3: Distribute the Remaining Electrons After forming the single bonds, we are left with 10 - 2(2) = 6 electrons. We distribute these electrons by forming a triple bond between carbon and nitrogen. The Lewis structure for \(\mathrm{HCN}\) is: H - C ≡ N

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Most popular questions from this chapter

An important observation supporting the concept of resonance in the localized electron model was that there are only three different structures of dichlorobenzene \(\left(\mathrm{C}_{6} \mathrm{H}_{4} \mathrm{Cl}_{2}\right)\). How does this fact support the concept of resonance? (See Exercise \(91 .\) )

Lewis structures can be used to understand why some molecules react in certain ways. Write the Lewis structures for the reactants and products in the reactions described below. a. Nitrogen dioxide dimerizes to produce dinitrogen tetroxide. b. Boron trihydride accepts a pair of electrons from ammonia, forming \(\mathrm{BH}_{3} \mathrm{NH}_{3}\). Give a possible explanation for why these two reactions occur.

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Predict the molecular structure (including bond angles) for each of the following. a. \(\mathrm{SeO}_{3}\) b. \(\mathrm{SeO}_{2}\)

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