Chapter 8: Problem 83
Write Lewis structures that obey the octet rule for each of the following molecules. a. \(\mathrm{CCl}_{4}\) c. \(\mathrm{SeCl}_{2}\) b. \(\mathrm{NCl}_{3}\) d. ICl In each case, the atom listed first is the central atom.
Chapter 8: Problem 83
Write Lewis structures that obey the octet rule for each of the following molecules. a. \(\mathrm{CCl}_{4}\) c. \(\mathrm{SeCl}_{2}\) b. \(\mathrm{NCl}_{3}\) d. ICl In each case, the atom listed first is the central atom.
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Get started for freeConsider the following: \(\operatorname{Li}(s)+\frac{1}{2} \mathrm{I}_{2}(g) \rightarrow \operatorname{LiI}(s) \Delta H=\) \(-292 \mathrm{~kJ} . \mathrm{LiI}(s)\) has a lattice energy of \(-753 \mathrm{~kJ} / \mathrm{mol}\). The ionization energy of \(\operatorname{Li}(g)\) is \(520 . \mathrm{kJ} / \mathrm{mol}\), the bond energy of \(\mathrm{I}_{2}(g)\) is \(151 \mathrm{~kJ} / \mathrm{mol}\), and the electron affinity of \(\mathrm{I}(g)\) is \(-295 \mathrm{~kJ} / \mathrm{mol}\). Use these data to determine the heat of sublimation of \(\operatorname{Li}(s)\).
Some of the important pollutants in the atmosphere are ozone \(\left(\mathrm{O}_{3}\right)\), sulfur dioxide, and sulfur trioxide. Write Lewis structures for these three molecules. Show all resonance structures where applicable.
Predict the molecular structure (including bond angles) for each of the following. (See Exercises 111 and \(112 .\) ) a. \(\mathrm{XeCl}_{2}\) b. \(\mathrm{ICl}_{3}\) c. \(\mathrm{TeF}_{4}\) d. \(\mathrm{PCl}_{5}\)
Which member of the following pairs would you expect to be more energetically stable? Justify each choice. a. \(\mathrm{NaBr}\) or \(\mathrm{NaBr}_{2}\) b. \(\mathrm{ClO}_{4}\) or \(\mathrm{ClO}_{4}^{-}\) c. \(\mathrm{SO}_{4}\) or \(\mathrm{XeO}_{4}\) d. \(\mathrm{OF}_{4}\) or \(\mathrm{SeF}_{4}\)
Which of the following statements is(are) true? Correct the false statements. a. It is impossible to satisfy the octet rule for all atoms in \(\mathrm{XeF}_{2}\) b. Because \(\mathrm{SF}_{4}\) exists, \(\mathrm{OF}_{4}\) should also exist because oxygen is in the same family as sulfur. c. The bond in \(\mathrm{NO}^{+}\) should be stronger than the bond in \(\mathrm{NO}^{-}\) d. As predicted from the two Lewis structures for ozone, one oxygen-oxygen bond is stronger than the other oxygenoxygen bond.
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