Chapter 9: Problem 19
Use the localized electron model to describe the bonding in \(\mathrm{H}_{2} \mathrm{CO}\) (carbon is the central atom).
Chapter 9: Problem 19
Use the localized electron model to describe the bonding in \(\mathrm{H}_{2} \mathrm{CO}\) (carbon is the central atom).
All the tools & learning materials you need for study success - in one app.
Get started for freeWhy are \(d\) orbitals sometimes used to form hybrid orbitals? Which period of elements does not use \(d\) orbitals for hybridization? If necessary, which \(d\) orbitals \((3 d, 4 d, 5 d\), or \(6 d)\) would sulfur use to form hybrid orbitals requiring \(d\) atomic orbitals? Answer the same question for arsenic and for iodine.
What are molecular orbitals? How do they compare with atomic orbitals? Can you tell by the shape of the bonding and antibonding orbitals which is lower in energy? Explain.
The \(\mathrm{N}_{2} \mathrm{O}\) molecule is linear and polar. a. On the basis of this experimental evidence, which arrangement, NNO or NON, is correct? Explain your answer. b. On the basis of your answer to part a, write the Lewis structure of \(\mathrm{N}_{2} \mathrm{O}\) (including resonance forms). Give the formal charge on each atom and the hybridization of the central atom. c. How would the multiple bonding in \(\mathrm{N} \equiv \mathrm{N}-\ddot{\mathrm{O}}\) : be described in terms of orbitals?
Cyanamide \(\left(\mathrm{H}_{2} \mathrm{NCN}\right)\), an important industrial chemical, is produced by the following steps: $$ \begin{aligned} \mathrm{CaC}_{2}+\mathrm{N}_{2} & \longrightarrow \mathrm{CaNCN}+\mathrm{C} \\\ \mathrm{CaNCN} & \stackrel{\text { Acid }}{\longrightarrow} \mathrm{H}_{2} \mathrm{NCN} \\ \text { Cyanamide } \end{aligned} $$ Calcium cyanamide (CaNCN) is used as a direct-application fertilizer, weed killer, and cotton defoliant. It is also used to make cyanamide, dicyandiamide, and melamine plastics: Dicyandiamide not shown) a. Write Lewis structures for \(\mathrm{NCN}^{2-}, \mathrm{H}_{2} \mathrm{NCN}\), dicyandiamide, and melamine, including resonance structures where appropriate. b. Give the hybridization of the \(\mathrm{C}\) and \(\mathrm{N}\) atoms in each species. c. How many \(\sigma\) bonds and how many \(\pi\) bonds are in each species? d. Is the ring in melamine planar? e. There are three different \(\mathrm{C}-\mathrm{N}\) bond distances in dicyandiamide, \(\mathrm{NCNC}\left(\mathrm{NH}_{2}\right)_{2}\), and the molecule is nonlinear. Of all the resonance structures you drew for this molecule, predict which should be the most important.
Compare and contrast bonding molecular orbitals with antibonding molecular orbitals.
What do you think about this solution?
We value your feedback to improve our textbook solutions.