Rank these intermolecular forces in terms of their typical relative strengths: hydrogen bonding; dipole-dipole; induced dipole-induced dipole.

Short Answer

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The ranking of these intermolecular forces in terms of their relative strengths is: Hydrogen bonding > Dipole-dipole > Induced dipole-induced dipole.

Step by step solution

01

Understanding Intermolecular Forces

Intermolecular forces are forces of attraction between molecules, and they are weaker than the intramolecular forces that hold atoms together within a molecule. They can largely affect the physical properties of substances such as boiling point, melting point, and vapor pressure. There are three types to understand: 1. Hydrogen Bonding: This is a special type of dipole-dipole attraction between molecules where hydrogen is bound to a highly electronegative atom (such as nitrogen, oxygen or fluorine), and this hydrogen is attracted to another electronegative atom in another molecule. 2. Dipole-dipole forces: These occur when the positive end of a polar molecule is attracted to the negative end of another polar molecule. They are stronger than induced dipole-induced dipole forces but weaker than hydrogen bonding. 3. Induced dipole-induced dipole forces: These are also known as London dispersion forces and they are the weakest intermolecular forces. They occur in all molecules, polar and nonpolar, due to the shifting electron cloud which can create a temporary partial charge.
02

Ranking The Forces

The types of intermolecular forces can be ranked according to their strength as follows: hydrogen bonding > dipole-dipole > induced dipole-induced dipole. Hydrogen bonding is generally the strongest of the three because it involves a hydrogen atom which is very strongly attracted to an electronegative atom, creating a strong polar bond. Dipole-dipole forces are the next strongest. These forces occur between polar molecules where there is an electronegativity difference greater than 0.5 but the molecules do not involve hydrogen. Induced dipole-induced dipole forces are the weakest intermolecular forces. These interactions become more significant as the size and shape of the molecules increase.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Hydrogen Bonding
Hydrogen bonding represents a significant type of intermolecular force that greatly influences the behavior of molecules. Specifically, hydrogen bonding occurs when a hydrogen atom, which is covalently bonded to a highly electronegative atom like nitrogen, oxygen, or fluorine, experiences attraction to another electronegative atom in a different molecule.

Importantly, hydrogen bonds are directional and account for many of the unique properties of water, like its high boiling point compared to other molecules of similar size. Examples in biological systems include DNA base pairs and protein structures, where hydrogen bonds help maintain stability and structure.

Features of Hydrogen Bonding

  • Electronegativity: A key player in hydrogen bonding where larger differences in electronegativity enhance the bond strength.
  • Directionality: The bonds tend to be linear, aligning the positive end of the hydrogen to the negative charge of the electronegative atom, maximizing attraction.
  • Significant Implications: Properties like surface tension, capillarity, and thermal properties of water are influenced by hydrogen bonds.
Dipole-Dipole Interactions
Dipole-dipole interactions are pivotal forces in the context of intermolecular attractions. They occur between molecules that have permanent dipole moments, which means that the molecules have regions of positive and negative charge due to uneven distribution of electrons across the molecule.

These interactions are stronger when the molecules are closer and the dipole moment is greater, thus affecting the physical properties such as melting points and boiling points of compounds. Polar solvents like water facilitate strong dipole-dipole interactions, which helps to dissolve ionic compounds and other polar substances.

Understanding Dipole Moments

  • Permanent Dipoles: Result from the unequal sharing of electrons in polar covalent bonds.
  • Molecule Orientation: The positive end of one molecule is attracted to the negative end of another, aligning the dipoles in a favorable position.
London Dispersion Forces
London dispersion forces, also known as induced dipole-induced dipole interactions, are the weakest form of intermolecular forces. Nonetheless, they are universal, occurring in all molecular substances, irrespective of whether the molecules are polar or nonpolar.

These forces arise due to the momentary distributions of electron density within molecules, which can induce transient dipoles, leading to attractions between molecules. They become more pronounced with heavier and larger atoms because they have more electrons which can contribute to stronger momentary dipoles.

Impact on Physical Properties

  • Influence on Nonpolar Molecules: Though these forces are weak, they are critical for determining the properties of nonpolar compounds.
  • Role in Larger Molecules: In substances like noble gases and nonpolar organic molecules, dispersion forces are the only forces at play and dictate state changes like boiling and melting points.

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