Chapter 19: Problem 5
In terms of AVEE, explain why Na is more likely to form \(\mathrm{Na}^{+}\) than \(\mathrm{O}\) is to form \(\mathrm{O}^{+}\)
Short Answer
Expert verified
It is more likely that Na will form \(\mathrm{Na}^{+}\) due to its lower Ionization energy or AVEE as compared to O. This is because the valence electron of Na that needs to be removed is further away from the nucleus and less tightly held by its charge, requiring less energy to remove.
Step by step solution
01
Understanding AVEE for Sodium (Na)
Consider the atomic structure of sodium. It's in the first group of the Periodic Table, meaning it has one electron in its outermost shell. Removing this one electron to form \(\mathrm{Na}^{+}\) will involve relatively less energy because the valence electron is farther from the nucleus and not so tightly held by its charge. Therefore, the Atomic Valence electron energy (AVEE) or Ionization energy would be relatively lower.
02
Understanding AVEE for Oxygen (O)
Now consider the atomic structure of oxygen. It's in the sixth group of the Periodic Table, which means it has six electrons in its outermost shell. The electrons in oxygen's outer shell are closer to the nucleus and more tightly held by its charge compared to sodium. This means that removing an electron to form \(\mathrm{O}^{+}\) would require more energy, indicating a higher AVEE or Ionization energy.
03
Comparative Analysis
Comparing the AVEE of Na and O, it is clear that less energy is required to ionize Na than it is to ionize O due to the atomic structure and the position of valence electrons in these atoms. Thus, it is more likely for Na to form \(\mathrm{Na}^{+}\) than for O to form \(\mathrm{O}^{+}\).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionization Energy
Ionization energy is the energy required to remove an electron from an atom in its gaseous state. It is a crucial concept in chemistry because it helps predict an atom's reactivity and its ability to form ions. For example, sodium (Na) has a lower ionization energy compared to oxygen (O). This means it takes less energy to remove the outermost electron from a sodium atom than from an oxygen atom. This property is particularly important when considering the likelihood of ion formation; atoms with low ionization energies are more likely to form positive ions.
As one progresses across the periodic table, ionization energies tend to increase. This is because the atomic radius decreases, pulling the electrons closer to the nucleus and increasing the energy needed to overcome this attraction. Understanding ionization energy allows students to predict which elements will more readily lose electrons and form positive ions, facilitating a deeper grasp of chemical bonding and reactions.
As one progresses across the periodic table, ionization energies tend to increase. This is because the atomic radius decreases, pulling the electrons closer to the nucleus and increasing the energy needed to overcome this attraction. Understanding ionization energy allows students to predict which elements will more readily lose electrons and form positive ions, facilitating a deeper grasp of chemical bonding and reactions.
Periodic Table Groups
The periodic table is organized into groups and periods, with the groups running vertically. Each group contains elements that have the same number of valence electrons, which are the electrons in the outermost shell of an atom. These valence electrons are integral to an atom's chemical properties, including how it bonds with other atoms. For instance, group 1 elements have one valence electron and are highly reactive, often forming +1 ions like \( \mathrm{Na}^{+} \). Group 6 elements, such as oxygen, have six valence electrons and are more likely to gain electrons when forming compounds.
Understanding the layout of the periodic table and periodic trends, like changes in ionization energy and atomic size, can significantly aid students in analyzing elements' propensities for ion formation and chemical reactivity. This knowledge is foundational for exercises dealing with ionic compounds and electron transfer.
Understanding the layout of the periodic table and periodic trends, like changes in ionization energy and atomic size, can significantly aid students in analyzing elements' propensities for ion formation and chemical reactivity. This knowledge is foundational for exercises dealing with ionic compounds and electron transfer.
Valence Electrons
Valence electrons are the electrons that reside in the outermost shell of an atom. They play a pivotal role in the chemical bonding process because they are the electrons involved in forming bonds with other atoms. Elements with a full valence shell are typically less reactive, as seen with noble gases, which have eight valence electrons and are known for their stability. In contrast, elements with just one valence electron, like sodium (Na), are highly reactive and can easily lose that electron to achieve a more stable electron configuration, resulting in the formation of a positive ion, \( \mathrm{Na}^{+} \).
By understanding the concept of valence electrons, students can predict the types of ions an element is likely to form. This understanding is integral to mastering topics related to atomic structure, such as AVEE, as well as ionic and covalent bonding.
By understanding the concept of valence electrons, students can predict the types of ions an element is likely to form. This understanding is integral to mastering topics related to atomic structure, such as AVEE, as well as ionic and covalent bonding.
Formation of Positive Ions
The formation of positive ions, or cations, occurs when an atom loses one or more of its valence electrons. This process is influenced by the atom's ionization energy and is common for metals in the periodic table that have relatively low ionization energies. Elements like sodium (Na) find it energetically favorable to lose an electron, thus transforming into positive ions such as \( \mathrm{Na}^{+} \). Conversely, non-metals or elements with high ionization energies are less likely to form positive ions.
In summary, the likelihood of an element forming a positive ion is greater for those with fewer valence electrons and lower ionization energies, which are often positioned on the left side of the periodic table. Understanding these tendencies assists students in predicting ion formation and their subsequent arrangements in ionic compounds, laying the foundation for comprehending more complex chemical behaviors.
In summary, the likelihood of an element forming a positive ion is greater for those with fewer valence electrons and lower ionization energies, which are often positioned on the left side of the periodic table. Understanding these tendencies assists students in predicting ion formation and their subsequent arrangements in ionic compounds, laying the foundation for comprehending more complex chemical behaviors.