Oxidation numbers, also known as oxidation states, are assigned to elements in chemical compounds to keep track of electron distribution. The oxidation number is a theoretical charge on an atom if the compound were to be broken down into its constituent atoms, assigning shared electrons to the more electronegative element. Several rules help assign oxidation numbers:
- The oxidation number of an element in its elemental form is always zero.
- For monatomic ions, the oxidation number is equal to the charge on the ion.
- Oxygen generally has an oxidation number of -2 in compounds, except in peroxides or bonded to fluorine.
- Hydrogen typically has an oxidation number of +1 when bonded with nonmetals and -1 with metals.
- The sum of oxidation numbers in a neutral compound is zero, and in a polyatomic ion, it is equal to the ion charge.
By determining oxidation numbers, one can identify which atoms are oxidized and which are reduced in a redox reaction. Changes in these numbers during the reaction reflect the movement of electrons.