The bond between the \(\mathrm{N}\) atom and \(\mathrm{Br}\) atom must be weakened or broken for reaction 2 to proceed upon collision of two ONBr molecules. Note that a violent collision between two ONBr molecules is more likely to weaken or break the bonds than a gentle collision. Based on this idea, explain why there will be more collisions that will be effective in weakening or breaking the \(\mathrm{N}-\mathrm{Br}\) bond at high temperature compared to low temperature.

Short Answer

Expert verified
With an increase in temperature, the kinetic energy of the molecules increases. This leads to more violent and frequent collisions, increasing the probability that the collisions will weaken or break the N-Br bond, thus allowing the reaction to proceed.

Step by step solution

01

Define Collision Theory

Collision Theory explains how chemical reactions occur and why rates of reaction alter. For a reaction to occur, particles ought to collide with a certain minimum energy, known as the activation energy.
02

Understand the effect of temperature on kinetic energy

An increase in temperature means an increase in the kinetic energy of the particles. This makes particles move faster, leading to more frequent collisions.
03

Make the connection between kinetic energy and activation energy

When temperature increases, not only do particles collide more frequently, but they also do so with greater energy. This increases the likelihood that the collisions will have enough energy to overcome the activation energy (the energy barrier to reaction). Therefore, at higher temperatures, more collisions will have the necessary energy to break the N-Br bond.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Kinetics
Chemical kinetics is the branch of chemistry that studies the rate and flow of chemical processes. It provides insights into how different variables such as concentration, pressure, and, notably, temperature affect the rate at which reactions occur. Understanding kinetics helps us control reactions in industrial processes, predict product yields, and sometimes even prevent unwanted reactions that could be dangerous.

At its core, kinetic theory is concerned with the movement and energy of particles. It leans on the fundamental principle that only when particles collide with sufficient energy they can react. A substance's reaction rate is dictated by the frequency and the energy of these collisions. If we imagine each reaction as a hurdle race, the kinetics would tell us how fast and with what energy the hurdles can be scaled by the reactants.
Activation Energy
Activation energy is akin to a threshold that must be surpassed for a chemical reaction to take place. It's the minimum energy required to transform reactants into products during a chemical reaction. Visually, you might imagine activation energy as the height of a hill that reactants must climb over to become products. If the reactants don’t have enough kinetic energy, they will collide but not react, much like a car that doesn't have enough gas to get over a hill.

Activation energy serves as a barrier to reaction, preventing molecules from reacting every time they collide. It ensures that only molecules with enough energy to result in a reaction - and hence the formation of products - succeed. This concept underscores the selectivity of chemical reactions and plays a key role in understanding how different factors, especially temperature, influence reaction rates.
Effect of Temperature on Reaction Rate
Temperature significantly impacts the rate of chemical reactions. As temperature increases, the particles involved gain kinetic energy and move more vigorously. This heightened energy translates to more frequent and more forceful collisions, increasing the likelihood that the collisions will exceed the activation energy. Consequently, higher temperatures can lead to a greater number of successful reactions in a given time period.

It's helpful to think of temperature as the vigor behind each collision. At higher temperatures, reactant molecules are like athletes on stimulants: they move faster and collide more energetically, making it more likely for reactions to occur. In the case of our ONBr molecules, the heat turns their 'gentle nudges' into 'forceful bumps', enabling them to break the N-Br bonds and react.
Kinetic Energy in Chemistry
Kinetic energy in chemistry relates to the energy of motion of particles. It is a key factor because it determines how hard particles will collide during a chemical reaction. The greater the kinetic energy of the molecules, the more forceful the collisions will be. In a way, kinetic energy is the currency for chemical changes; without enough of it, there is no trade, i.e., no reaction.

This energy is influenced by factors such as temperature, as we've learned: hotter temperatures mean higher kinetic energy. When revisiting the Collision Theory with a focus on kinetic energy, we can see it is not just the number of collisions that matter, but the quality of those collisions - their energy - which makes the difference in whether a reaction will proceed or not.

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