Chapter 2: Problem 66
Determine whether or not each element is a transition element. a. \(\mathrm{Cr}\) b. Br c. Mo d. Cs
Short Answer
Expert verified
Chromium (Cr) and Molybdenum (Mo) are transition elements, while Bromine (Br) and Caesium (Cs) are not.
Step by step solution
01
- Definition of Transition Elements
Understand that transition elements are the elements found in Groups 3 to 12 of the Periodic Table, which correspond to the d-block. They have partially filled d subshells.
02
- Identify the Group Placement for Chromium (Cr)
Check the Periodic Table to find where Chromium (Cr) is located. Chromium is in Group 6, which is within Groups 3 to 12, meaning it has a partially filled d subshell.
03
- Identify the Group Placement for Bromine (Br)
Check the Periodic Table and find the placement for Bromine (Br). Bromine is in Group 17, which is not within Groups 3 to 12. Therefore, it doesn't have a partially filled d subshell, and is not a transition element.
04
- Identify the Group Placement for Molybdenum (Mo)
Look at the Periodic Table and locate Molybdenum (Mo). Molybdenum is in Group 6, which is within Groups 3 to 12, indicating it has a partially filled d subshell.
05
- Identify the Group Placement for Caesium (Cs)
Find Caesium (Cs) on the Periodic Table. Caesium is in Group 1, which is outside Groups 3 to 12. It doesn’t have a partially filled d subshell, so it is not a transition element.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Periodic Table
The Periodic Table is a comprehensive chart that organizes all known elements according to their atomic number and electron configuration. The table is divided into several blocks, including the s-block, p-block, d-block, and f-block.
The structure of the Periodic Table is critical for understanding an element's properties. For instance, the table is arranged so that elements with similar chemical behaviors fall within the same column, known as a group or family.
Group numbering starts from 1 to 18, stretching from the leftmost side (hydrogen) to the rightmost side (noble gases). The elements in each group typically exhibit trends in electron affinity, electronegativity, and ionization energies. Learning about the Periodic Table is foundational to chemistry, as it provides invaluable insight into how elements behave and interact.
The structure of the Periodic Table is critical for understanding an element's properties. For instance, the table is arranged so that elements with similar chemical behaviors fall within the same column, known as a group or family.
Group numbering starts from 1 to 18, stretching from the leftmost side (hydrogen) to the rightmost side (noble gases). The elements in each group typically exhibit trends in electron affinity, electronegativity, and ionization energies. Learning about the Periodic Table is foundational to chemistry, as it provides invaluable insight into how elements behave and interact.
d-block elements
d-block elements, also known as transition metals, are located in the central portion of the Periodic Table and occupy Groups 3 to 12. These elements are characterized by their partially filled d subshells, which can include one to nine d electrons.
Transition metals are known for their ability to form various oxidation states, their colorful compounds, and for being good conductors of heat and electricity. Elements like iron (Fe), copper (Cu), and gold (Au) are well-known examples of d-block elements.
The chemistry of these elements is often more complex due to the presence of d electrons. They can participate in the formation of coordination compounds, where transition metals bind to other atoms, called ligands, in a geometric arrangement. This aspect is crucial in fields like catalysis and material science.
Transition metals are known for their ability to form various oxidation states, their colorful compounds, and for being good conductors of heat and electricity. Elements like iron (Fe), copper (Cu), and gold (Au) are well-known examples of d-block elements.
The chemistry of these elements is often more complex due to the presence of d electrons. They can participate in the formation of coordination compounds, where transition metals bind to other atoms, called ligands, in a geometric arrangement. This aspect is crucial in fields like catalysis and material science.
partially filled d subshell
A partially filled d subshell means that there are electrons present in the d orbital, but it's not completely filled with its maximum of 10 electrons. This characteristic is the defining feature of transition elements and is essential for their unique properties.
For example, the color of compounds made by transition elements is often due to electronic transitions involving d electrons. Moreover, the variable oxidation states that these elements can achieve are due to the removal of d electrons during chemical reactions.
The concept of a partially filled d subshell provides a deep understanding of the behavior of transition metals in chemical bonding and reactions. It explains why these elements can form such a diverse array of compounds with different properties and applications.
For example, the color of compounds made by transition elements is often due to electronic transitions involving d electrons. Moreover, the variable oxidation states that these elements can achieve are due to the removal of d electrons during chemical reactions.
The concept of a partially filled d subshell provides a deep understanding of the behavior of transition metals in chemical bonding and reactions. It explains why these elements can form such a diverse array of compounds with different properties and applications.