What is internal energy? Is internal energy a state function?

Short Answer

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Internal energy is the total microscopic energy of a system and is considered a state function since it depends only on the system's current state.

Step by step solution

01

Definition of Internal Energy

Internal energy of a system is the total energy stored within the system. It encompasses all forms of energy that are microscopic in nature, including kinetic and potential energies of the particles within the system. This energy is not observable directly but can be measured in terms of changes when a system undergoes a process.
02

Explaining State Function

A state function is a property of a system that depends only on the current state of the system, not on the path or the manner in which the system arrived at that state. State functions include properties like temperature, pressure, volume, and enthalpy.
03

Internal Energy as a State Function

Internal energy is a state function because it depends only on the state of the system. The change in internal energy does not depend on how the system reached its current state, but solely on the initial and final states. This means the change in internal energy is the same, no matter the path taken from initial to final state.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

State Function
When you delve into the field of thermodynamics, you frequently encounter the term 'state function'. This might sound complex at first, but it's a fundamental concept that greatly simplifies understanding thermodynamic systems. Think of a state function as being similar to a pin on a map. Regardless of which route you took to reach that pin, its location remains the same.

In thermodynamics, properties like temperature, pressure, volume, and enthalpy are state functions. When you measure such a property, you're assessing the current 'position' of the system on its energy map. A system’s journey to this point is irrelevant to this value. This is crucial for simplifying calculations because it allows you to analyze processes irrespective of the path taken.
System's Total Energy
Now, let's talk about internal energy, which is essentially the 'total energy' of a system. This term often conjures up images of huge power plants or complex chemical reactions, but it's just as applicable to something as small as a cup of coffee warming your hands. Your system, in this case, could be the coffee, the cup, and even the air around it, all of which contain energy.

There’s a knack to figuring out a system's total energy. It includes all forms of energy within the system, both those you can see like the movement of steam from your cup, and those you can't, like the vibrational energy of the molecules in the coffee. The total energy is significant because it's what you calculate to understand how energy moves in and out of your system.
Microscopic Forms of Energy
The 'microscopic forms of energy' within a system can seem invisible and untouchable, yet they're as real as the screen in front of you. In the microscopic realm, you'd find molecules dancing and atoms vibrating, all holding energy in various forms.

At this minute scale, kinetic energy is all about the hustle and bustle of particles moving and colliding. Meanwhile, potential energy can be thought of as stored energy, waiting to be unleashed—imagine it like tiny springs wound up between atoms and molecules. These forms of energy might be unseen, but they’re what heat up your soup and keep stars shining. Understanding these microscopic forms is like reading a secret code that explains why matter behaves the way it does.

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Most popular questions from this chapter

Calculate \(\Delta H_{\mathrm{rxn}}\) for the reaction: $$ \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) \longrightarrow 2 \mathrm{Fe}(s)+3 \mathrm{CO}_{2}(g) $$ Use the following reactions and given \(\Delta H^{\prime}\) s: \(2 \mathrm{Fe}(s)+3 / 2 \mathrm{O}_{2}(g) \longrightarrow \mathrm{Fe}_{2} \mathrm{O}_{3}(s) \quad \Delta H=-824.2 \mathrm{~kJ}\) $$\mathrm{CO}(g)+{ }^{1} /{ }_{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g) \quad \Delta H=-282.7\mathrm{~kJ}$$

The heating value of combustible fuels is evaluated based on the quantities known as the higher heating value (HHV) and the lower heating value (LHV). The HHV has a higher absolute value and assumes that the water produced in the combustion reaction is formed in the liquid state. The LHV has a lower absolute value and assumes that the water produced in the combustion reaction is formed in the gaseous state. The LHV is therefore the sum of the HHV (which is negative) and the heat of vaporization of water for the number of moles of water formed in the reaction (which is positive). The table lists the enthalpy of combustion which is equivalent to the HHV-for several closely related hydrocarbons. $$\begin{array}{lc} \text { Hydrocarbon } & \Delta H_{\text {comb }}(\mathrm{kJ} / \mathrm{mol}) \\\ \mathrm{CH}_{4}(\mathrm{~g}) & -890 \\ \hline \mathrm{C}_{2} \mathrm{H}_{6}(\mathrm{~g}) & -1560 \\ \hline \mathrm{C}_{3} \mathrm{H}_{8}(\mathrm{~g}) & -2219 \\ \hline \mathrm{C}_{4} \mathrm{H}_{10}(\mathrm{~g}) & -2877 \\ \hline \mathrm{C}_{5} \mathrm{H}_{12}(I) & -3509 \\ \hline \mathrm{C}_{6} \mathrm{H}_{14}(I) & -4163 \\ \hline \mathrm{C}_{7} \mathrm{H}_{16}(I) & -4817 \\ \hline \mathrm{C}_{8} \mathrm{H}_{18}(I) & -5470 \\ \hline\end{array}$$ Use the information in the table to answer the following questions. a. Write two balanced equations for the combustion of \(\mathrm{C}_{3} \mathrm{H}_{8}\) one assuming the formation of liquid water and the other assuming the formation of gaseous water. b. Given that the heat of vaporization of water is \(44.0 \mathrm{~kJ} / \mathrm{mol}\), what is \(\Delta H_{\mathrm{rxn}}\) for each reaction in part a? Which quantity is the HHV? The LHV? c. When propane is used to cook in an outdoor grill, is the amount of heat released the HHV or the LHV? What amount of heat is released upon combustion of \(1.00 \mathrm{~kg}\) of propane in an outdoor grill? d. For each \(\mathrm{CH}_{2}\) unit added to a hydrocarbon, what is the average increase in the absolute value of \(\Delta H_{\mathrm{comb}} ?\)

Explain how the high specific heat capacity of water can affect the weather in coastal regions.

What is pressure-volume work? How is it calculated?

A system releases \(622 \mathrm{~kJ}\) of heat and does \(105 \mathrm{~kJ}\) of work on the surroundings. What is the change in internal energy of the system?

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