Which of the following will have the lowest total vapor pressure at
\(25^{\circ} \mathrm{C} ?\)
a. pure water (vapor pressure \(=23.8\) torr at \(25^{\circ} \mathrm{C}\) )
b. a solution of glucose in water with \(\chi_{\mathrm{C}_{\mathrm{s}}
\mathrm{H}_{\mathrm{l} 2} \mathrm{O}_{\mathrm{s}}}=0.01\)
c. a solution of sodium chloride in water with \(\chi_{\mathrm{NaCl}}=0.01\)
d. a solution of methanol in water with \(\chi_{\mathrm{CH_{3}},
\mathrm{OH}}=0.2\) (Consider the vapor pressure of both methanol \([143\) torr at
\(\left.25^{\circ} \mathrm{C}\right]\) and water.