Chapter 10: Problem 15
Calculate the sodium ion concentration when \(70.0 \mathrm{mL}\) of 3.0 \(M\) sodium carbonate is added to \(30.0 \mathrm{mL}\) of \(1.0 \mathrm{M}\) sodium bicarbonate.
Chapter 10: Problem 15
Calculate the sodium ion concentration when \(70.0 \mathrm{mL}\) of 3.0 \(M\) sodium carbonate is added to \(30.0 \mathrm{mL}\) of \(1.0 \mathrm{M}\) sodium bicarbonate.
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Get started for freeIn flushing and cleaning columns used in liquid chromatography to remove adsorbed contaminants, a series of solvents is used. Hexane \(\left(\mathrm{C}_{6} \mathrm{H}_{14}\right),\) chloroform \(\left(\mathrm{CHCl}_{3}\right),\) methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right),\) and water are passed through the column in that order. Rationalize the order in terms of intermolecular forces and the mutual solubility (miscibility) of the solvents.
Rationalize the trend in water solubility for the following simple alcohols: $$\begin{array}{lc} \text { Alcohol } & \begin{array}{c} \text { Solubility } \\ \left(\mathrm{g} / 100 \mathrm{g} \mathrm{H}_{2} \mathrm{O} \text { at } 20^{\circ} \mathrm{C}\right) \end{array} \\ \hline \text { Methanol, } \mathrm{CH}_{3} \mathrm{OH} & \text { Soluble in all proportions } \\ \text { Ethanol, } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH} & \text { Soluble in all proportions } \\ \text { Propanol, } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH} & \text { Soluble in all proportions } \\ \text { Butanol, } \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{2} \mathrm{OH} & 8.14 \\ \text { Pentanol, } \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{CH}_{2} \mathrm{OH} & 2.64 \\ \text { Hexanol, } \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{CH}_{2} \mathrm{OH} & 0.59 \\ \text { Heptanol, } \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{CH}_{2} \mathrm{OH} & 0.09 \\ \hline \end{array}$$
For an acid or a base, when is the normality of a solution equal to the molarity of the solution and when are the two concentration units different?
Plants that thrive in salt water must have internal solutions (inside the plant cells) that are isotonic with (have the same osmotic pressure as) the surrounding solution. A leaf of a saltwater plant is able to thrive in an aqueous salt solution (at \(25^{\circ} \mathrm{C}\) ) that has a freezing point equal to \(-0.621^{\circ} \mathrm{C}\). You would like to use this information to calculate the osmotic pressure of the solution in the cell. a. In order to use the freezing-point depression to calculate osmotic pressure, what assumption must you make (in addition to ideal behavior of the solutions, which we will assume)? b. Under what conditions is the assumption (in part a) reasonable? c. Solve for the osmotic pressure (at \(25^{\circ} \mathrm{C}\) ) of the solution in the plant cell. d. The plant leaf is placed in an aqueous salt solution (at \(\left.25^{\circ} \mathrm{C}\right)\) that has a boiling point of \(102.0^{\circ} \mathrm{C}\). What will happen to the plant cells in the leaf?
A solution of phosphoric acid was made by dissolving \(10.0 \mathrm{g}\) \(\mathrm{H}_{3} \mathrm{PO}_{4}\) in \(100.0 \mathrm{mL}\) water. The resulting volume was \(104 \mathrm{mL}\) Calculate the density, mole fraction, molarity, and molality of the solution. Assume water has a density of \(1.00 \mathrm{g} / \mathrm{cm}^{3}\).
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