Which solvent, water or hexane \(\left(\mathrm{C}_{6} \mathrm{H}_{14}\right),\) would you choose to dissolve each of the following? a. \(\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}\) b. \(\mathrm{CS}_{2}\) c. \(\mathrm{CH}_{3} \mathrm{OH}\) d. \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{16} \mathrm{CH}_{2} \mathrm{OH}\) e.\(\mathrm HCl\) {f .} \( \mathrm{C}_{6} \mathrm{H}_{6}\)

Short Answer

Expert verified
a. Water b. Hexane c. Water d. Hexane e. Water f. Hexane

Step by step solution

01

Identifying compound polarity

Copper nitrate, Cu(NO3)2, is an ionic compound because it consists of a metal (Cu) and a polyatomic ion (NO3−). Ionic compounds are generally considered to be polar.
02

Choosing the appropriate solvent

Since Cu(NO3)2 is polar, it will dissolve better in the polar solvent water than in the nonpolar solvent hexane. #b. CS2#
03

Identifying compound polarity

Carbon disulfide, CS2, is a nonpolar compound as the electronegativity difference between carbon and sulfur is small.
04

Choosing the appropriate solvent

Since CS2 is nonpolar, it will dissolve better in the nonpolar solvent hexane than in the polar solvent water. #c. CH3OH#
05

Identifying compound polarity

Methanol, CH3OH, is a polar compound because the oxygen atom forms a polar bond with the hydrogen atom due to their significant electronegativity difference.
06

Choosing the appropriate solvent

Since CH3OH is polar, it will dissolve better in the polar solvent water than in the nonpolar solvent hexane. #d. CH3(CH2)16CH2OH#
07

Identifying compound polarity

This molecule, which is a long-chain alcohol, is largely nonpolar because it consists of a long hydrocarbon chain. The hydroxyl group at the end of the molecule is polar, but its contribution to the overall polarity of the molecule is fairly small due to the size of the hydrocarbon chain.
08

Choosing the appropriate solvent

Since the hydrocarbon chain dominates the overall polarity of the molecule, it is considered more nonpolar than polar. Therefore, it will dissolve better in the nonpolar solvent hexane than in the polar solvent water. #e. HCl#
09

Identifying compound polarity

Hydrogen chloride, HCl, is a polar compound due to the significant electronegativity difference between hydrogen and chlorine atoms.
10

Choosing the appropriate solvent

Since HCl is polar, it will dissolve better in the polar solvent water than in the nonpolar solvent hexane. #f. C6H6#
11

Identifying compound polarity

Benzene, C6H6, is a nonpolar compound as it consists of a symmetrical ring of carbon and hydrogen atoms that create an overall equal distribution of electron density.
12

Choosing the appropriate solvent

Since C6H6 is nonpolar, it will dissolve better in the nonpolar solvent hexane than in the polar solvent water.

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Most popular questions from this chapter

Calculate the molarity and mole fraction of acetone in a \(1.00-m\) solution of acetone \(\left(\mathrm{CH}_{3} \mathrm{COCH}_{3}\right)\) in ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right) .\) (Density of acetone \(=0.788 \mathrm{g} / \mathrm{cm}^{3} ;\) density of ethanol \(=0.789\) \(\mathrm{g} / \mathrm{cm}^{3} .\) ) Assume that the volumes of acetone and ethanol add.

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