Chapter 17: Problem 25
When jump-starting a car with a dead battery, the ground jumper should be attached to a remote part of the engine block. Why?
Chapter 17: Problem 25
When jump-starting a car with a dead battery, the ground jumper should be attached to a remote part of the engine block. Why?
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Get started for freeWhat is electrochemistry? What are redox reactions? Explain the difference between a galvanic and an electrolytic cell.
A solution containing \(\mathrm{Pt}^{4+}\) is electrolyzed with a current of 4.00 A. How long will it take to plate out \(99 \%\) of the platinum in 0.50 L of a \(0.010-M\) solution of \(\mathrm{Pt}^{4+} ?\)
Which of the following statement(s) is/are true? a. Copper metal can be oxidized by \(\mathrm{Ag}^{+}\) (at standard conditions). b. In a galvanic cell the oxidizing agent in the cell reaction is present at the anode. c. In a cell using the half reactions \(A l^{3+}+3 e^{-} \longrightarrow A l\) and \(\mathrm{Mg}^{2+}+2 \mathrm{e}^{-} \longrightarrow \mathrm{Mg},\) aluminum functions as the anode. d. In a concentration cell electrons always flow from the compartment with the lower ion concentration to the compartment with the higher ion concentration. e. In a galvanic cell the negative ions in the salt bridge flow in the same direction as the electrons.
What is the maximum work that can be obtained from a hydrogen-oxygen fuel cell at standard conditions that produces \(1.00 \mathrm{kg}\) water at \(25^{\circ} \mathrm{C} ?\) Why do we say that this is the maximum work that can be obtained? What are the advantages and disadvantages in using fuel cells rather than the corresponding combustion reactions to produce electricity?
An electrochemical cell consists of a nickel metal electrode immersed in a solution with \(\left[\mathrm{Ni}^{2+}\right]=1.0 \mathrm{M}\) separated by a porous disk from an aluminum metal electrode immersed in a solution with \(\left[\mathrm{Al}^{3+}\right]=1.0 \mathrm{M} .\) Sodium hydroxide is added to the aluminum compartment, causing \(\mathrm{Al}(\mathrm{OH})_{3}(s)\) to precipitate. After precipitation of Al(OH) \(_{3}\) has ceased, the concentration of \(\mathrm{OH}^{-}\) is \(1.0 \times 10^{-4} \mathrm{M}\) and the measured cell potential is \(1.82 \mathrm{V}\). Calculate the \(K_{\mathrm{sp}}\) value for \(\mathrm{Al}(\mathrm{OH})_{3}\) $$ \mathrm{Al}(\mathrm{OH})_{3}(s) \rightleftharpoons \mathrm{Al}^{3+}(a q)+3 \mathrm{OH}^{-}(a q) \quad K_{\mathrm{sp}}=? $$
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