Calculate the amount of energy released per gram of hydrogen nuclei reacted for the following reaction. The atomic masses are \(^{1}_{1}{H}, 1.00782 \mathrm{u} ; \frac{2}{1} \mathrm{H}, 2.01410 \mathrm{u} ;\) and an electron, \(5.4858 \times\) \(10^{-4}\) u. (Hint: Think carefully about how to account for the electron mass.)$$\mathrm{i} \mathrm{H}+\mathrm{i} \mathrm{H} \longrightarrow_{\mathrm{i}}^{2} \mathrm{H}+_{+\mathrm{i}}^{0}$$

Short Answer

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The energy released per gram of hydrogen nuclei reacted for the given reaction can be calculated by first finding the mass difference between the initial reactants and final products, then converting the mass difference into energy using Einstein's equation, and finally converting the energy per reaction to energy per gram of hydrogen nuclei reacted. Following these steps, we find that the energy released per gram of hydrogen nuclei reacted is: Energy released per gram = Energy released per reaction × Number of reactions in 1 gram of hydrogen nuclei

Step by step solution

01

Write down the given reaction and identify the initial reactants and final products

The given reaction can be written as: \(^{1}_{1}\mathrm{H} + ^{1}_{1}\mathrm{H} \longrightarrow ^{2}_{1}\mathrm{H} + e^-\) In this reaction: - Initial reactants are: \(^{1}_{1}\mathrm{H}\) and \(^{1}_{1}\mathrm{H}\) - Final products are: \(_{1}^{2}\mathrm{H}\) and \(e^-\)
02

Find the mass difference between the initial reactants and final products

To calculate the mass difference, we need to subtract the total mass of the final products from the total mass of the initial reactants. Mass of initial reactants = \(2 \times 1.00782 \mathrm{u}\) (since two \(^{1}_{1}\mathrm{H}\) are reacted) Mass of final products = \(1 \times 2.01410 \mathrm{u} + 1 \times 5.4858 \times 10^{-4} \mathrm{u}\) (one \(_{1}^{2}\mathrm{H}\) and one \(e^-\)) Now, let's calculate the mass difference: Mass difference = Mass of initial reactants - Mass of final products Mass difference = \((2 \times 1.00782) - (2.01410 + 5.4858 \times 10^{-4}) \mathrm{u}\)
03

Convert the mass difference into energy

Now we will use Einstein's expression, \(E = mc^2\), to convert the mass difference into energy. Here, \(c\) is the speed of light, which is approximately \(3 \times 10^8 \mathrm{m.s^{-1}}\). First, let's convert the mass difference from unified atomic mass units (u) to kilograms (kg), using the conversion factor \(1.66054 \times 10^{-27}\mathrm{kg.u^{-1}}\): Mass difference = Mass difference in u × \(1.66054 \times 10^{-27}\mathrm{kg.u^{-1}}\) Now we can calculate the energy using \(E = mc^2\): Energy released = Mass difference × \((3 \times 10^8)^2 \mathrm{m^2.s^{-2}}\)
04

Calculate the energy released per gram of hydrogen nuclei reacted

We were asked to find the amount of energy released per gram of reacting hydrogen nuclei. Since we have calculated the energy released per reaction, we can now convert it into energy per gram. First, we need to find the mass of 1 gram of hydrogen nuclei in terms of the number of hydrogen nuclei: 1 gram of hydrogen nuclei = \(\frac{1 \mathrm{g}}{1.00782 \mathrm{u} \times 1.66054 \times 10^{-27} \mathrm{kg.u^{-1}}}\) Now, we multiply the energy released per reaction by the number of reactions in 1 gram of hydrogen nuclei: Energy released per gram = Energy released per reaction × Number of reactions in 1 gram of hydrogen nuclei

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