Chapter 19: Problem 69
Although He is the second most abundant element in the universe, it is very rare on the earth. Why?
Chapter 19: Problem 69
Although He is the second most abundant element in the universe, it is very rare on the earth. Why?
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Get started for freeMany structures of phosphorus-containing compounds are drawn with some \(P=O\) bonds. These bonds are not the typical \(\pi\) bonds we've considered, which involve the overlap of two \(p\) orbitals. Instead, they result from the overlap of a \(d\) orbital on the phosphorus atom with a \(p\) orbital on oxygen. This type of \(\pi\) bonding is sometimes used as an explanation for why \(\mathrm{H}_{3} \mathrm{PO}_{3}\) has the first structure below rather than the second:Draw a picture showing how a \(d\) orbital and a \(p\) orbital overlap to form a \(\pi\) bond.
Write a balanced equation describing the reaction of aluminum metal with concentrated aqueous sodium hydroxide.
Write the Lewis structure for \(\mathrm{O}_{2} \mathrm{F}_{2}\). Predict the bond angles and hybridization of the two central oxygen atoms. Assign oxidation states and formal charges to the atoms in \(\mathrm{O}_{2} \mathrm{F}_{2} .\) The compound \(\mathrm{O}_{2} \mathrm{F}_{2}\) is a vigorous and potent oxidizing and fluorinating agent. Are oxidation states or formal charges more useful in accounting for these properties of \(\mathrm{O}_{2} \mathrm{F}_{2} ?\)
Nitrogen gas reacts with hydrogen gas to form ammonia gas \(\left(\mathrm{NH}_{3}\right) .\) Consider the following illustration representing the original reaction mixture in a \(15.0 \mathrm{L}\) container (the numbers of each molecule shown are relative numbers):Assume this reaction mixture goes to completion. The piston apparatus allows the container volume to change in order to keep the pressure constant at 1.00 atm. Assume ideal behavior and constant temperature. a. What is the partial pressure of ammonia in the container when the reaction is complete? b. What is the mole fraction of ammonia in the container when the reaction is complete? c. What is the volume of the container when the reaction is complete?
Besides the central atom, what are the differences between \(\mathrm{CO}_{2}\) and \(\mathrm{SiO}_{2} ?\)
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