Chapter 19: Problem 82
In large doses, selenium is toxic. However, in moderate intake, selenium is a physiologically important element. How is selenium physiologically important?
Chapter 19: Problem 82
In large doses, selenium is toxic. However, in moderate intake, selenium is a physiologically important element. How is selenium physiologically important?
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Get started for freeDiscuss the importance of the \(\mathrm{C}-\mathrm{C}\) and \(\mathrm{Si}-\mathrm{Si}\) bond strengths and of \(\pi\) bonding to the properties of carbon and silicon.
How do the acidities of the aqueous solutions of the alkaline earth metal ions \(\left(\mathrm{M}^{2+}\right)\) change in going down the group?
While selenic acid has the formula \(\mathrm{H}_{2} \mathrm{SeO}_{4}\) and thus is directly related to sulfuric acid, telluric acid is best visualized as \(\mathrm{H}_{6} \mathrm{TeO}_{6}\) or \(\mathrm{Te}(\mathrm{OH})_{6}\) a. What is the oxidation state of tellurium in \(\operatorname{Te}(\mathrm{OH})_{6} ?\) b. Despite its structural differences with sulfuric and selenic acid, telluric acid is a diprotic acid with \(\mathrm{p} K_{\mathrm{a}_{1}}=7.68\) and \(\mathrm{p} K_{\mathrm{a}_{2}}=11.29 .\) Telluric acid can be prepared by hydrolysis of tellurium hexafluoride according to the equation $$\operatorname{TeF}_{6}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow\operatorname{Te}(\mathrm{OH})_{6}(a q)+6 \mathrm{HF}(a q)$$ Tellurium hexafluoride can be prepared by the reaction of elemental tellurium with fluorine gas:$$\operatorname{Te}(s)+3 \mathrm{F}_{2}(g) \longrightarrow \operatorname{Te} \mathrm{F}_{6}(g)$$.If a cubic block of tellurium (density \(=6.240 \mathrm{g} / \mathrm{cm}^{3}\) ) measuring \(0.545 \mathrm{cm}\) on edge is allowed to react with 2.34 L fluorine gas at 1.06 atm and \(25^{\circ} \mathrm{C}\), what is the \(\mathrm{pH}\) of a solution of \(\mathrm{Te}(\mathrm{OH})_{6}\) formed by dissolving the isolated \(\operatorname{Te} \mathrm{F}_{6}(g)\) in \(115 \mathrm{mL}\) solution? Assume \(100 \%\) yield in all reactions.
How long will it take to produce \(1.00 \times 10^{3} \mathrm{kg}\) of magnesium metal by the electrolysis of molten magnesium chloride using a current of \(5.00 \times 10^{4} \mathrm{A} ?\)
Calculate the solubility of \(\mathrm{Mg}(\mathrm{OH})_{2}\left(K_{\mathrm{sp}}=8.9 \times 10^{-12}\right)\) in an aqueous solution buffered at \(\mathrm{pH}=9.42\).
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