Chapter 2: Problem 12
In going across a row of the periodic table, electrons are added and ionization energy generally increases. In going down a column of the periodic table, electrons are also being added but ionization energy decreases. Explain.
Chapter 2: Problem 12
In going across a row of the periodic table, electrons are added and ionization energy generally increases. In going down a column of the periodic table, electrons are also being added but ionization energy decreases. Explain.
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Get started for freeThe electron affinities of the elements from aluminum to chlorine are \(-44,-120,-74,-200.4,\) and \(-384.7 \mathrm{kJ} / \mathrm{mol},\) respectively. Rationalize the trend in these values.
The ionization energy for a \(1 s\) electron in a silver atom is \(2.462 \times 10^{6} \mathrm{kJ} / \mathrm{mol}\) a. Determine an approximate value for \(Z_{\text {eff }}\) for the Ag \(1 s\) electron. Assume the Bohr model applies to the 1 s electron. \(Z_{\mathrm{eff}}\) is the apparent nuclear charge experienced by the electrons. b. How does \(Z_{\text {eff }}\) from part a compare to \(Z\) for Ag? Rationalize the relative numbers.
Answer the following questions, assuming that \(m_{s}\) could have three values rather than two and that the rules for \(n, \ell,\) and \(m_{\ell}\) are the normal ones. a. How many electrons would an orbital be able to hold? b. How many elements would the first and second periods in the periodic table contain? c. How many elements would be contained in the first transition metal series? d. How many electrons would the set of \(4 f\) orbitals be able to hold?
Calculate the wavelength of light emitted when each of the following transitions occur in the hydrogen atom. What type of electromagnetic radiation is emitted in each transition? a. \(n=4 \rightarrow n=3\) b. \(n=5 \rightarrow n=4\) c. \(n=5 \rightarrow n=3\)
The electron affinity for sulfur is more negative than that for oxygen. How do you account for this?
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