Calculate the wavelength of light emitted when each of the following transitions occur in the hydrogen atom. What type of electromagnetic radiation is emitted in each transition? a. \(n=3 \rightarrow n=2\) b. \(n=4 \rightarrow n=2\) c. \(n=2 \rightarrow n=1\)

Short Answer

Expert verified
In conclusion, the wavelengths and types of electromagnetic radiation emitted for each transition are as follows: a. For the transition \(n=3 \rightarrow n=2\), the emitted light has a wavelength of 656 nm (visible light). b. For the transition \(n=4 \rightarrow n=2\), the emitted light has a wavelength of 486 nm (visible light). c. For the transition \(n=2 \rightarrow n=1\), the emitted light has a wavelength of 122 nm (ultraviolet light).

Step by step solution

01

Understand the energy level formula and constants for hydrogen atom.

The energy level of a hydrogen atom for an electron in a state with principal quantum number n is given by the formula: \(E_n = -\frac{13.6 eV}{n^2}\) To calculate the energy released during a transition, first, we need to calculate the difference in energy levels (∆E) between the two energy levels, then convert the energy difference into the emitted wavelength using the formula: \(E = h \cdot c / \lambda\) Where E is the energy, h is the Planck's constant (4.135 x 10^-15 eV·s), c is the speed of light (3 x 10^8 m/s), and λ (lambda) is the wavelength of the light emitted. For each transition, we will calculate the energy difference and then find the corresponding wavelength of the emitted light using the constants Planck's constant and the speed of light.
02

Calculate the energy difference for transition a.(\(n=3 \rightarrow n=2\))

Using the energy level formula, calculate the energy levels for n=3 and n=2: \(E_3 = -\frac{13.6 eV}{(3)^2} = -\frac{13.6 eV}{9} = -1.51 eV\) \(E_2 = -\frac{13.6 eV}{(2)^2} = -\frac{13.6 eV}{4} = -3.4 eV\) Now, we can calculate the energy difference (∆E) for the transition: \(\Delta E = E_3 - E_2 = -1.51 eV - (-3.4 eV) = 1.89 eV\)
03

Calculate the wavelength for transition a.

Now we will use the energy difference and the constants to find the emitted wavelength: \(1.89 eV = \frac{4.135 \times 10^{-15} eV\cdot s \cdot 3\times10^8 m/s}{\lambda}\) Solving for λ, \(\lambda = \frac{4.135 \times 10^{-15} eV\cdot s \cdot 3\times10^8 m/s}{1.89 eV} = 6.56 \times 10^{-7} m\) Converting the wavelength to nm (1 m = 10^9 nm): \(\lambda = 656 nm\)
04

Identify the type of electromagnetic radiation for transition a.

With the calculated wavelength of 656 nm, which falls in the visible light range (400-700nm), we can identify that the electromagnetic radiation emitted for transition a is a visible light.
05

Repeat Steps 2-4 for transition b. (\(n=4 \rightarrow n=2\)) and transition c. (\(n=2 \rightarrow n=1\)).

Repeat the above calculations for the remaining transitions and identify the type of electromagnetic radiation for each. Transition b: 1. Energy difference: ∆E = 2.55 eV 2. Wavelength: λ = 486 nm 3. Type of electromagnetic radiation: Visible light Transition c: 1. Energy difference: ∆E = 10.2 eV 2. Wavelength: λ = 122 nm 3. Type of electromagnetic radiation: Ultraviolet light In conclusion, for transition a (\(n=3 \rightarrow n=2\)), the emitted light has a wavelength of 656 nm and falls in the visible light range; for transition b (\(n=4 \rightarrow n=2\)), with a wavelength of 486 nm, it is also visible light; and for transition c (\(n=2 \rightarrow n=1\)), the emitted light has a wavelength of 122 nm, which falls in the ultraviolet light range.

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