Chapter 20: Problem 21
Write electron configurations for the following metals. a. Ni b. Cd c. Zr d. Os
Chapter 20: Problem 21
Write electron configurations for the following metals. a. Ni b. Cd c. Zr d. Os
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Get started for freeTetrahedral complexes of \(\mathrm{Co}^{2+}\) are quite common. Use a \(d\) -orbital splitting diagram to rationalize the stability of \(\mathrm{Co}^{2+}\) tetrahedral complex ions.
Name the following coordination compounds. a. \(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Br}\right] \mathrm{Br}_{2}\) b. \(\mathrm{Na}_{3}\left[\mathrm{Co}(\mathrm{CN})_{6}\right]\) c. \(\left[\mathrm{Fe}\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\right)_{2}\left(\mathrm{NO}_{2}\right)_{2}\right] \mathrm{Cl}\) d. \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{I}_{2}\right]\left[\mathrm{PtI}_{4}\right]\)
The complex ion \(\mathrm{PdCl}_{4}^{2-}\) is diamagnetic. Propose a structure for \(\mathrm{PdCl}_{4}^{2-}\)
What roles do kinetics and thermodynamics play in the effect that the following reaction has on the properties of steel? $$ 3 \mathrm{Fe}+\mathrm{C} \rightleftharpoons \mathrm{Fe}_{3} \mathrm{C} $$
A certain first-row transition metal ion forms many different colored solutions. When four coordination compounds of this metal, each having the same coordination number, are dissolved in water, the colors of the solutions are red, yellow, green, and blue. Further experiments reveal that two of the complex ions are paramagnetic with four unpaired electrons and the other two are diamagnetic. What can be deduced from this information about the four coordination compounds?
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