Chapter 21: Problem 27
Give the structure for each of the following. a. 3 -hexene b. \(2,4-\) heptadiene c. 2 -methyl- 3 -octene
Short Answer
Expert verified
a. \(H_2C{=}CH-CH_2-CH_2-CH_2-CH_3\)
b. \(H_2C{=}CH-CH{=}CH-CH_2-CH_2-CH_3\)
c. \(H_3C-CH(CH_3)-CH{=}CH-CH_2-CH_2-CH_2-CH_3\)
Step by step solution
01
Identify the main carbon chain
Hexene indicates that we have a six-carbon chain (hex-) with a double bond (-ene). Since the double bond starts at carbon 3 (3-hexene), we can draw the structure as follows:
\(H_2C{=}CH-CH_2-CH_2-CH_2-CH_3\)
b. 2,4-heptadiene
02
Identify the main carbon chain
Heptadiene indicates that we have a seven-carbon chain (hept-) with two double bonds (-diene). The double bonds start at carbons 2 and 4 (2,4-heptadiene), so we can draw the structure like this:
\(H_2C{=}CH-CH{=}CH-CH_2-CH_2-CH_3\)
c. 2-methyl-3-octene
03
Identify the main carbon chain
Octene indicates that we have an eight-carbon chain (oct-) with a double bond (-ene). The double bond starts at carbon 3 (3-octene), and there is a methyl group (-CH_3) attached to carbon 2 (2-methyl). We can draw the structure as follows:
\(
H_3C-CH(CH_3)-CH{=}CH-CH_2-CH_2-CH_2-CH_3
\)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Alkenes
Alkenes are a type of hydrocarbon that contain at least one carbon-carbon double bond. The presence of this double bond is a defining characteristic and affects the chemical properties of the molecule. In the simplest alkene, ethene (C2H4), the carbon atoms are connected by a double bond, and each carbon is also bonded to two hydrogen atoms.
When naming alkenes, the suffix '-ene' is used to indicate the presence of this double bond. The position of the double bond is specified by a number placed in front of the alkene name. For instance, '3-hexene' has the double bond starting at the third carbon of a six-carbon chain.
Alkenes follow the general formula \( C_nH_{2n} \), showing that they have two hydrogen atoms less than alkanes (which have single bonds only). This unsaturation allows alkenes to participate in a variety of reactions, such as addition reactions, making them chemically versatile and important in organic synthesis.
When naming alkenes, the suffix '-ene' is used to indicate the presence of this double bond. The position of the double bond is specified by a number placed in front of the alkene name. For instance, '3-hexene' has the double bond starting at the third carbon of a six-carbon chain.
Alkenes follow the general formula \( C_nH_{2n} \), showing that they have two hydrogen atoms less than alkanes (which have single bonds only). This unsaturation allows alkenes to participate in a variety of reactions, such as addition reactions, making them chemically versatile and important in organic synthesis.
Alkadienes
Alkadienes, or dienes for short, are hydrocarbons that have two carbon-carbon double bonds in their structure. The naming of alkadienes incorporates similar rules to that of alkenes but with an emphasis on indicating the presence of two double bonds. This is done by using the prefix 'di-', along with the '-ene' suffix to identify the compound as an alkadiene.
In '2,4-heptadiene', the numbers '2,4' indicate the starting positions of the double bonds along the seven-carbon chain. Notation of multiple bonded positions is separated by commas and placed before the name of the hydrocarbon chain.
The presence of multiple double bonds in alkadienes adds complexity to their reactivity and can lead to various isomers depending on the positions and cis/trans configurations of the double bonds. These compounds play a significant role in polymer chemistry, where they can form intricate structures and materials with diverse properties.
In '2,4-heptadiene', the numbers '2,4' indicate the starting positions of the double bonds along the seven-carbon chain. Notation of multiple bonded positions is separated by commas and placed before the name of the hydrocarbon chain.
The presence of multiple double bonds in alkadienes adds complexity to their reactivity and can lead to various isomers depending on the positions and cis/trans configurations of the double bonds. These compounds play a significant role in polymer chemistry, where they can form intricate structures and materials with diverse properties.
Structural Formula
The structural formula represents the arrangement of atoms within a molecule. Unlike the molecular formula, which tells us only the number of each type of atom, the structural formula provides insight into how those atoms are connected. For organic compounds, showing the arrangement of carbon and hydrogen atoms, as well as any functional groups, is crucial to understanding their chemical behavior.
For example, the structural formula for '2-methyl-3-octene' incorporates not only the main eight-carbon chain of an alkene but also an additional methyl group (CH3) attached to the second carbon atom. This level of detail can reveal the relative positioning of groups and the potential for chemical reactions.
Correctly interpreting structural formulas is an essential skill in organic chemistry, as it allows students and chemists to visualize molecules and predict how they might interact with other substances. The line-angle formula, which simplifies the depiction by showing carbon bonds as lines and carbon atoms as the ends or intersections of lines (hydrogen atoms are often omitted for simplicity), is a common way to represent organic structures for clarity and ease of interpretation.
For example, the structural formula for '2-methyl-3-octene' incorporates not only the main eight-carbon chain of an alkene but also an additional methyl group (CH3) attached to the second carbon atom. This level of detail can reveal the relative positioning of groups and the potential for chemical reactions.
Correctly interpreting structural formulas is an essential skill in organic chemistry, as it allows students and chemists to visualize molecules and predict how they might interact with other substances. The line-angle formula, which simplifies the depiction by showing carbon bonds as lines and carbon atoms as the ends or intersections of lines (hydrogen atoms are often omitted for simplicity), is a common way to represent organic structures for clarity and ease of interpretation.