Chapter 21: Problem 28
Give the structure for each of the following. a. 4 -methyl- 1 -pentyne b. 2,3,3 -trimethyl- 1 -hexene c. 3 -ethyl- 4 -decene
Chapter 21: Problem 28
Give the structure for each of the following. a. 4 -methyl- 1 -pentyne b. 2,3,3 -trimethyl- 1 -hexene c. 3 -ethyl- 4 -decene
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Get started for freeA compound containing only carbon and hydrogen is \(85.63 \%\) C by mass. Reaction of this compound with \(\mathrm{H}_{2} \mathrm{O}\) produces a secondary alcohol as the major product and a primary alcohol as the minor product. (See Exercise 62.) If the molar mass of the hydrocarbon is between 50 and 60 g/mol, name the compound.
What are the structural differences between \(\alpha\) - and \(\beta\) -glucose? These two cyclic forms of glucose are the building blocks to form two different polymers. Explain.
For the following formulas, what types of isomerism could be exhibited? For each formula, give an example that illustrates the specific type of isomerism. The types of isomerism are structural, geometric, and optical. a. \(C_{6} H_{12}\) b. \(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O} \quad\) c. \(\mathrm{C}_{6} \mathrm{H}_{4} \mathrm{Br}_{2}\)
When acrylic polymers are burned, toxic fumes are produced. For example, in many airplane fires, more passenger deaths have been caused by breathing toxic fumes than by the fire itself. Using polyacrylonitrile as an example, what would you expect to be one of the most toxic, gaseous combustion products created in the reaction?
Choose one of the following terms to match the description 1 given in statements \((1)-(17) .\) All of the following pertain to proteins or carbohydrates. a. aldohexose b. saliva c. cellulose d. \(\mathrm{CH}_{2} \mathrm{O}\) e. cysteine f. denaturation g. disaccharides h. disulfide i. globular j. glycogen k. glycoside linkage I. hydrophobic m. ketohexoses n. oxytocin o. pleated sheet p. polypeptide q. primary structure (1) polymer consisting of many amino acids (2) linkage that forms between two cysteine species (3) peptide hormone that triggers milk secretion (4) proteins with roughly spherical shape (5) sequence of amino acids in a protein (6) silk protein secondary structure (7) water-repelling amino acid side chain (8) amino acid responsible for permanent wave in hair (9) breakdown of a protein's tertiary and/or secondary structure (10) animal polymer of glucose (11) \(-\mathrm{C}-\mathrm{O}-\mathrm{C}-\) bond between rings in disaccharide sugars (12) empirical formula leading to the name carbohydrate (13) where enzymes catalyzing the breakdown of glycoside linkages are found (14) six-carbon ketone sugars (15) structural component of plants, polymer of glucose (16) sugars consisting of two monomer units (17) six-carbon aldehyde sugars
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