Chapter 21: Problem 40
Draw all the structural and geometrical (cis-trans) isomers of bromochloropropene.
Chapter 21: Problem 40
Draw all the structural and geometrical (cis-trans) isomers of bromochloropropene.
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Get started for freeFor the following formulas, what types of isomerism could be exhibited? For each formula, give an example that illustrates the specific type of isomerism. The types of isomerism are structural, geometric, and optical. a. \(C_{6} H_{12}\) b. \(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O} \quad\) c. \(\mathrm{C}_{6} \mathrm{H}_{4} \mathrm{Br}_{2}\)
Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1 -butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of \(\mathrm{H}^{+},\) an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. \(1-\) butanol \(\longrightarrow\) butane b. \(1-\) butanol \(\longrightarrow 2\) -butanone
The average molar mass of one base pair of nucleotides in DNA is approximately 600 g/mol. The spacing between successive base pairs is about \(0.34 \mathrm{nm},\) and a complete turn in the helical structure of DNA occurs about every \(3.4 \mathrm{nm}\). If a DNA molecule has a molar mass of \(4.5 \times 10^{9} \mathrm{g} / \mathrm{mol}\), approximately how many complete turns exist in the DNA \(\alpha\)-helix structure?
Give the structure for each of the following. a. 3 -hexene b. \(2,4-\) heptadiene c. 2 -methyl- 3 -octene
Give an example reaction that would yield the following products. Name the organic reactant and product in each reaction. a. alkane b. monohalogenated alkane c. dihalogenated alkane d. tetrahalogenated alkane e. monohalogenated benzene f. alkene
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