Chapter 21: Problem 58
Draw a structural formula for each of the following. a. 3 -methylpentanoic acid b. ethyl methanoate c. methyl benzoate d. 3 -chloro- 2,4 -dimethylhexanoic acid
Chapter 21: Problem 58
Draw a structural formula for each of the following. a. 3 -methylpentanoic acid b. ethyl methanoate c. methyl benzoate d. 3 -chloro- 2,4 -dimethylhexanoic acid
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Get started for freeIf one hydrogen in a hydrocarbon is replaced by a halogen atom, the number of isomers that exist for the substituted compound depends on the number of types of hydrogen in the original hydrocarbon. Thus there is only one form of chloroethane (all hydrogens in ethane are equivalent), but there are two isomers of propane that arise from the substitution of a methyl hydrogen or a methylene hydrogen. How many isomers can be obtained when one hydrogen in each of the compounds named below is replaced by a chlorine atom? a. \(n\) -pentane c. 2,4 -dimethylpentane b. 2 -methylbutane d. methylcyclobutane
Three important classes of biologically important natural polymers are discussed. What are the three classes, what are the monomers used to form the polymers, and why are they biologically important?
Reagents such as HCI, HBr, and HOH (H_O) can add across carbon-carbon double and triple bonds, with H forming a bond to one of the carbon atoms in the multiple bond and \(\mathrm{Cl}, \mathrm{Br},\) or OH forming a bond to the other carbon atom in the multiple bond. In some cases, two products are possible. For the major organic product, the addition occurs so that the hydrogen atom in the reagent attaches to the carbon atom in the multiple bond that already has the greater number of hydrogen atoms bonded to it. With this rule in mind, draw the structure of the major product in each of the following reactions. a. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}_{2}+\mathrm{H}_{2} \mathrm{O} \stackrel{\mathrm{H}^{2}}{\longrightarrow}\) b. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}_{2}+\mathrm{HBr} \longrightarrow\) c. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}+2 \mathrm{HBr} \longrightarrow\)
Isoprene is the repeating unit in natural rubber. The structure of isoprene is a. Give a systematic name for isoprene. b. When isoprene is polymerized, two polymers of the form are possible. In natural rubber, the cis configuration is found. The polymer with the trans configuration about the double bond is called gutta percha and was once used in the manufacture of golf balls. Draw the structure of natural rubber and gutta percha showing three repeating units and the configuration about the carbon-carbon double bonds.
All amino acids have at least two functional groups with acidic or basic properties. In alanine, the carboxylic acid group has \(K_{a}=4.5 \times 10^{-3}\) and the amino group has \(K_{b}=7.4 \times 10^{-5}.\) Three ions of alanine are possible when alanine is dissolved in water. Which of these ions would predominate in a solution with \(\left[\mathrm{H}^{+}\right]=1.0 \mathrm{M} ?\) In a solution with \(\left[\mathrm{OH}^{-}\right]=1.0 \mathrm{M} ?\)
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