Chapter 21: Problem 90
How many different pentapeptides can be formed using five different amino acids?
Chapter 21: Problem 90
How many different pentapeptides can be formed using five different amino acids?
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Get started for freeIn glycine, the carboxylic acid group has \(K_{\mathrm{a}}=4.3 \times 10^{-3}\) and the amino group has \(K_{b}=6.0 \times 10^{-5} .\) Use these equilibrium constant values to calculate the cquilibrium constants for the following. a. \(^{+} \mathrm{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{3} \mathrm{O}^{+}\) b. \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H}+\mathrm{OH}^{-}\) c. \(\mathbf{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}\)
The Amoco Chemical Company has successfully raced a car with a plastic engine. Many of the engine parts, including piston skirts, connecting rods, and valve- train components, were made of a polymer called Torlon: What monomers are used to make this polymer?
Draw a structural formula for each of the following. a. 3 -methylpentanoic acid b. ethyl methanoate c. methyl benzoate d. 3 -chloro- 2,4 -dimethylhexanoic acid
Draw the structural formula for each of the following. a. 3 -isobutylhexane b. 2,2,4 -trimethylpentane, also called isooctane. This substance is the reference (100 level) for octane ratings. c. 2 -tert-butylpentane d. The names given in parts a and c are incorrect. Give the correct names for these hydrocarbons.
A polypeptide is also called a polyamide. Nylon is also an example of a polyamide. What is a polyamide? Consider a polyhydrocarbon, a polyester, and a polyamide. Assuming average chain lengths are equal, which polymer would you expect to make the strongest fibers and which polymer would you expect to make the weakest fibers? Explain.
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