Chapter 3: Problem 19
Describe the type of bonding that exists in the \(\mathrm{Cl}_{2}(g)\) molecule. How does this type of bonding differ from that found in the HCl(g) molecule? How is it similar?
Chapter 3: Problem 19
Describe the type of bonding that exists in the \(\mathrm{Cl}_{2}(g)\) molecule. How does this type of bonding differ from that found in the HCl(g) molecule? How is it similar?
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Get started for freeWrite Lewis structures for the following. Show all resonancestructures where applicable.a. \(\mathrm{NO}_{2}^{-}, \mathrm{NO}_{3}^{-}, \mathrm{N}_{2} \mathrm{O}_{4}\left(\mathrm{N}_{2} \mathrm{O}_{4} \text { exists as } \mathrm{O}_{2} \mathrm{N}-\mathrm{NO}_{2} .\right)\) b. \(\mathrm{OCN}^{-}, \mathrm{SCN}^{-}, \mathrm{N}_{3}^{-}\) (Carbon is the central atom in \(\mathrm{OCN}^{-}\) and \(\mathrm{SCN}^{-} .\) )
Arrange the following in order of increasing radius and increasing ionization energy. a. \(\mathrm{N}^{+}, \mathrm{N}, \mathrm{N}^{-}\) b. \(\mathrm{Se}, \mathrm{Se}^{-}, \mathrm{Cl}, \mathrm{Cl}^{+}\) c. \(\mathrm{Br}^{-}, \mathrm{Rb}^{+}, \mathrm{Sr}^{2+}\)
The designations \(1 \mathrm{A}\) through \(8 \mathrm{A}\) used for certain families of the periodic table are helpful for predicting the charges on ions in binary ionic compounds. In these compounds, the metals generally take on a positive charge equal to the family number, while the nonmetals take on a negative charge equal to the family number minus \(8 .\) Thus the compound between sodium and chlorine contains \(\mathrm{Na}^{+}\) ions and \(\mathrm{Cl}^{-}\) ions and has the formula NaCl. Predict the formula and the name of the binary compound formed from the following pairs of elements. a. Ca and N b. \(K\) and 0 c. \(\mathrm{Rb}\) and \(\mathrm{F}\) d. \(\mathrm{Mg}\) and \(\mathrm{S}\) e. Ba and I f. Al and Se g. Cs and \(P\) h. In and Br
Write Lewis structures for \(\mathrm{CO}_{3}^{2-}, \mathrm{HCO}_{3}^{-},\) and \(\mathrm{H}_{2} \mathrm{CO}_{3}\). When acid is added to an aqueous solution containing carbonate or bicarbonate ions, carbon dioxide gas is formed. We generally say that carbonic acid \(\left(\mathrm{H}_{2} \mathrm{CO}_{3}\right)\) is unstable. Use bond energies to estimate \(\Delta E\) for the reaction (in the gas phase) $$\mathrm{H}_{2} \mathrm{CO}_{3} \longrightarrow \mathrm{CO}_{2}+\mathrm{H}_{2} \mathrm{O}$$Specify a possible cause for the instability of carbonic acid.
The lattice energies of \(\mathrm{FeCl}_{3}, \mathrm{FeCl}_{2},\) and \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) are (in no particular order) \(-2631,-5359,\) and -14,774 kJ/mol. Match the appropriate formula to each lattice energy. Explain.
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