Chapter 3: Problem 2
The ionic compound \(A B\) is formed. The charges on the ions may be +1,\(-1 ;+2,-2 ;+3,-3 ;\) or even larger. What are the factors that determine the charge for an ion in an ionic compound?
Chapter 3: Problem 2
The ionic compound \(A B\) is formed. The charges on the ions may be +1,\(-1 ;+2,-2 ;+3,-3 ;\) or even larger. What are the factors that determine the charge for an ion in an ionic compound?
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Get started for freeName the compounds in parts a-d and write the formulas for the compounds in parts e-h. a. \(\mathrm{NaBr}\) b. \(\mathrm{Rb}_{2} \mathrm{O}\) c. CaS d. \(\mathrm{AlI}_{3}\) e. strontium fluoride f. aluminum selenide g. potassium nitride h. magnesium phosphide
The most common exceptions to the octet rule are compounds or ions with central atoms having more than eight electrons around them. \(\mathrm{PF}_{5}, \mathrm{SF}_{4}, \mathrm{ClF}_{3},\) and \(\mathrm{Br}_{3}^{-}\) are examples of this type of exception. Draw the Lewis structure for these compounds or ions. Which elements, when they have to, can have more than eight electrons around them? How is this rationalized?
Give the formula of a negative ion that would have the same number of electrons as each of the following positive ions. a. \(\mathrm{Na}^{+}\) b. \(\mathrm{Ca}^{2+}\) \(\mathbf{c} . \mathrm{Al}^{3+}\) d. \(\mathbf{R} \mathbf{b}^{+}\)
An alternative definition of electronegativity is Electronegativity \(=\) constant (I.E. \(-\) E.A.) where I.E. is the ionization energy and E.A. is the electron affinity using the sign conventions of this book. Use data in Chapter 2 to calculate the (I.E. \(-\) E.A.) term for \(\mathbf{F}, \mathbf{C l}, \mathbf{B r}\) and I. Do these values show the same trend as the electronegativity values given in this chapter? The first ionization energies of the halogens are \(1678,1255,1138,\) and \(1007 \mathrm{kJ} / \mathrm{mol},\) respectively. (Hint: Choose a constant so that the electronegativity of fluorine equals \(4.0 .\) Using this constant, calculate relative electronegativities for the other halogens and compare to values given in the text.)
For each of the following groups, place the atoms and/or ions in order of decreasing size. a. \(\mathrm{Cu}, \mathrm{Cu}^{+}, \mathrm{Cu}^{2+}\) b. \(\mathrm{Ni}^{2+}, \mathrm{Pd}^{2+}, \mathrm{Pt}^{2+}\) c. \(\mathrm{O}, \mathrm{O}^{-}, \mathrm{O}^{2-}\) d. \(\mathrm{La}^{3+}, \mathrm{Eu}^{3+}, \mathrm{Gd}^{3+}, \mathrm{Yb}^{3+}\) e. \(\mathrm{Te}^{2-}, \mathrm{I}^{-}, \mathrm{Cs}^{+}, \mathrm{Ba}^{2+}, \mathrm{La}^{3+}\)
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